A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

被引：96
|
作者：
Kong, Xiang-Jian [1 ,2 ,3 ]
Long, La-Sheng [1 ,2 ]
Huang, Rong-Bin [1 ,2 ]
Zheng, Lan-Sun [1 ,2 ]
Harris, T. David [4 ]
Zheng, Zhiping [1 ,2 ,3 ]
机构：
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[3] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
[4] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 29期
关键词：
CRYSTAL-STRUCTURES; MOLECULE; CORE; PD-145(CO)(X)(PET3)(30); MAGNETIZATION;
D O I：
10.1039/b822609a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(II) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3)(3)-Ni(NO3)(2) system using iminodiacetate as an ancillary ligand to control the hydrolysis.
引用
收藏
页码：4354 / 4356
页数：3
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