Flammability Tests and Investigations of Properties of Lignin-Containing Polymer Composites Based on Acrylates

被引：20
作者：
Podkoscielna, Beata [1 ]
Wnuczek, Krystyna [1 ]
Goliszek, Marta [1 ,2 ]
Klepka, Tomasz [3 ]
Dziuba, Kamil [4 ]
机构：
[1] Marie Curie Sklodowska Univ, Fac Chem, Inst Chem Sci, Dept Polymer Chem, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland
[2] Marie Curie Sklodowska Univ, Fac Chem, Inst Chem Sci, Analyt Lab, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland
[3] Lublin Univ Technol, Fac Mech Engn, Dept Technol & Polymer Proc, Nadbystrzycka 36, PL-20618 Lublin, Poland
[4] Marie Curie Sklodowska Univ, Fac Chem, Inst Chem Sci, Dept Organ Chem, M Curie Sklodowska Sq 3, PL-20031 Lublin, Poland
来源：
MOLECULES | 2020年 / 25卷 / 24期
关键词：
flammability tests; kraft lignin; diethyl vinylphosphonate; FLAME-RETARDANT; CELLULOSE;
D O I：
10.3390/molecules25245947
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In this paper flammability tests and detailed investigations of lignin-containing polymer composites' properties are presented. Composites were obtained using bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA.GDA), ethylene glycol dimethacrylate (EGDMA), and kraft lignin (lignin alkali, L) during UV curing. In order to evaluate the influence of lignin modification and the addition of flame retardant compounds on the thermal resistance of the obtained biocomposites, flammability tests have been conducted. After the modification with phosphoric acid (V) lignin, as well as diethyl vinylphosphonate, were used as flame retardant additives. The changes in the chemical structures (ATR-FTIR), as well as the influence of the different additives on the hardness, thermal (TG) and mechanical properties were discussed in detail. The samples after the flammability test were also studied to assess their thermal destruction.
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页数：20
相关论文
共 47 条
[1]   Sustainable Process for the Depolymerization/Oxidation of Softwood and Hardwood Kraft Lignins Using Hydrogen Peroxide under Ambient Conditions [J].
Ahmad, Zaid ;
Dajani, Waleed Wafa Al ;
Paleologou, Michael ;
Xu, Chunbao .
MOLECULES, 2020, 25 (10)
[2]   Preparation of Modified Hydrolysis Lignin and Its Use for Filling Epoxy Polymers and Enhancing Their Flame Resistance [J].
Alalykin, A. A. ;
Vesnin, R. L. ;
Kozulin, D. A. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (09) :1616-1622
[3]  
Brebu M, 2010, CELL CHEM TECHNOL, V44, P353
[4]  
Calvo-Flores F.G., 2010, LIGNIN LIGNANS RENEW, P1227
[5]   Influence of Ammonium Polyphosphate/Lignin Ratio on Thermal and Fire Behavior of Biobased Thermoplastic: The Case of Polyamide 11 [J].
Cayla, Aurelie ;
Rault, Francois ;
Giraud, Stephane ;
Salaun, Fabien ;
Sonnier, Rodolphe ;
Dumazert, Loic .
MATERIALS, 2019, 12 (07)
[6]   PLA with Intumescent System Containing Lignin and Ammonium Polyphosphate for Flame Retardant Textile [J].
Cayla, Aurelie ;
Rault, Francois ;
Giraud, Stephane ;
Salaun, Fabien ;
Fierro, Vanessa ;
Celzard, Alain .
POLYMERS, 2016, 8 (09)
[7]   Effect of cellulose, hemicellulose and lignin contents on pyrolysis and combustion of natural fibers [J].
Dorez, G. ;
Ferry, L. ;
Sonnier, R. ;
Taguet, A. ;
Lopez-Cuesta, J. -M. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 107 :323-331
[8]   Study of the Reactivity of Lignin Model Compounds to Fluorobenzylation Using 13C and 19F NMR: Application to Lignin Phenolic Hydroxyl Group Quantification by 19F NMR [J].
Esakkimuthu, Esakkiammal Sudha ;
Marlin, Nathalie ;
Brochier-Salon, Marie-Christine ;
Mortha, Gerard .
MOLECULES, 2020, 25 (14)
[9]   Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate [J].
Ferry, L. ;
Dorez, G. ;
Taguet, A. ;
Otazaghine, B. ;
Lopez-Cuesta, J. M. .
POLYMER DEGRADATION AND STABILITY, 2015, 113 :135-143
[10]   Suitability and Modification of Different Renewable Materials as Feedstock for Sustainable Flame Retardants [J].
Gebke, Stefan ;
Thuemmler, Katrin ;
Sonnier, Rodolphe ;
Tech, Soeren ;
Wagenfuehr, Andre ;
Fischer, Steffen .
MOLECULES, 2020, 25 (21)
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