Antimony Complexes {[2,6-(OMe)2C6H3]3SbCH2C(O)OEt}2+[Hg2I6]2- and {[2,6-(OMe)2C6H3]3SbMe}2+[HgI4]2-•DMSO: Synthesis and Structure

被引：6

作者：

Egorova, I., V ^{[1
]}

Zhidkov, V. V. ^{[1
]}

Grinishak, I. P. ^{[1
]}

Bagryanskaya, I. Yu ^{[2
,3
]}

Pervukhina, N., V ^{[3
,4
]}

Eltsov, I., V ^{[3
]}

Kurat'eva, N., V ^{[3
,4
]}

机构：

[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia

[2] Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

[3] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia

[4] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 64卷 / 01期

关键词：

tris(2,6-dimethoxyphenyl) antimony; ethyl iodoacetate; 1,4-diiodobutane; tris(2,6-dimethoxyphenyl) (ethoxycarbonylmethyl) antimony iodide; tris(2,6-dimethoxyphenyl) methyl antimony iodide; mercury diiodide; X-ray diffraction analysis; nuclear magnetic resonance; DONOR-ACCEPTOR COMPLEXES; ORGANO-VERBINDUNGEN; DERIVATIVES;

D O I：

10.1134/S0036023619010078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It has been established that ethyl iodoacelate and 1,4-diiodobutane alkylate triarylantimony Ar3Sb with the formation of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3Sb(CH2)(4)I]I-+(-), [Ar3Sb(CH2)(4)SbAr3]I-2+(2)- where Ar = 2,6-(OMe)(2)C6H3. The complexes [Ar3SbCH2C(O)OEt](2)(+)[Hg2I6](2) and [Ar3SbMe](2)(+)[HgI4](2) center dot DMSO have been synthesized by the reaction of [Ar3SbCH2C(O)OEt]I-+(-) and [Ar3SbMe]I-+(-) with mercury diiodide and studied by X-ray diffraction. The antimony and iodine atoms have a distorted tetrahedral coordination. The CSbC and IHgI angles are ranged within 103.28(14)degrees-116.68(14)degrees, 103.7(4)degrees-115.5(4)degrees and 98.122(9)degrees 125.590(12)degrees, 102.66(2)degrees-115.64(2)degrees, respectively.

引用

页码：28 / 35

页数：8

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