KINETICS AND MECHANISM OF THE OXIDATION OF DL-METHIONINE BY MORPHOLINIUM CHLOROCHROMATE

被引：0
|
作者：
Soni, N. [1 ]
Rao, P. P. [2 ]
Sharma, V. [1 ]
机构：
[1] Jai Narain Vyas Univ, Dept Chem, Jodhpur 342005, Rajasthan, India
[2] PBS Coll, Dept Chem, Vijaywada, Andhra Pradesh, India
来源：
OXIDATION COMMUNICATIONS | 2008年 / 31卷 / 04期
关键词：
halochromate; kinetics; mechanism; methionine; oxidation;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of methionine (Met) by morpholinium chlorochromate (MCC) in dimethylsulphoxide (DMSO) leads to the formation of the corresponding sulphoxide. The reaction is of first order with respect to each MCC and Met. The reaction is catalysed by hydrogen ions. The hydrogen-ion dependence has the form: k(obs) = a + b[H+]. The oxidation of methionine was studied in 19 different organic solvents. The solvent effect was analysed by the Kamlet's and Swain's multiparametric equations. Solvent effect indicated the importance of the cation-solvating power of the solvent. A suitable mechanism has also been postulated.
引用
收藏
页码：860 / 866
页数：7
相关论文
共 50 条
  • [21] Efficacy of liquid DL-methionine hydroxy analog free acid and DL-methionine as methionine sources for pigs
    Kim, B. G.
    Lindemann, M. D.
    Cromwell, G. L.
    Rademacher, M.
    JOURNAL OF ANIMAL SCIENCE, 2005, 83 : 66 - 66
  • [22] Kinetics and mechanism of oxidation of dimethyl sulfoxide by pyridinium chlorochromate
    Virkar, DD
    Gokavi, GS
    OXIDATION COMMUNICATIONS, 1999, 22 (04): : 532 - 537
  • [23] The kinetics and mechanism of the oxidation of seleno-DL- methionine by potassium ferrate
    John F. Read
    Anna E. H. Wyand
    Transition Metal Chemistry, 1998, 23 : 755 - 762
  • [24] Kinetics of oxidation of crotonaldehyde by tetraethylammonium chlorochromate
    Singh, JV
    Kumar, A
    Srivastava, K
    Mishra, K
    Pandey, A
    Agrawal, GL
    OXIDATION COMMUNICATIONS, 2004, 27 (04): : 849 - 853
  • [25] Kinetics and mechanism of oxidation of acrylic acid by tetraethylammonium chlorochromate in aqueous acetic acid
    Tomar, A.
    Kumar, A.
    OXIDATION COMMUNICATIONS, 2008, 31 (01): : 211 - 218
  • [26] Kinetics and mechanism of oxidation of secondary alcohols by 2,2′-bipyridinium chlorochromate
    Vyas, S
    Sharma, PK
    OXIDATION COMMUNICATIONS, 2001, 24 (02): : 248 - 256
  • [27] Kinetics and mechanism of the interaction of DL-methionine with cis-diaquaethylenediamine platinum(II) perchlorate in aqueous medium
    Shyamal Ghosh
    Parthasarathi Sengupta
    Gauri S. De
    Transition Metal Chemistry, 1999, 24 : 59 - 63
  • [28] Kinetics and mechanism of the interaction of DL-methionine with cis-diaquaethylenediamine platinum(lI) perchlorate in aqueous medium
    Ghosh, S
    Sengupta, P
    De, GS
    TRANSITION METAL CHEMISTRY, 1999, 24 (01) : 59 - 63
  • [29] Oxidation of Some Aliphatic Alcohols by Pyridinium Chlorochromate -Kinetics and Mechanism
    Jain, Sapana
    Hiran, B. L.
    Bhatt, C. V.
    E-JOURNAL OF CHEMISTRY, 2009, 6 (01) : 237 - 246
  • [30] OXIDATION STUDIES OF ALIPHATIC SECONDARY ALCOHOLS BY MORPHOLINIUM CHLOROCHROMATE. A KINETIC AND MECHANISTIC APPROACH
    Purohit, P.
    Kumbhani, S.
    Shastri, I.
    Sharma, P. K.
    OXIDATION COMMUNICATIONS, 2010, 33 (02): : 316 - 326
12345