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Synthesis of Poly-(R)-3 Hydroxyoctanoate (PHO) and Its Graphene Nanocomposites
被引:0
|作者:
Abdala, Ahmed
[1
]
Barrett, John
[1
]
Srienc, Friedrich
[1
]
机构:
[1] Petr Inst, Dept Chem Engn, Abu Dhabi, U Arab Emirates
来源:
GREEN POLYMER CHEMISTRY: BIOCATALYSIS AND MATERIALS II
|
2013年
/
1144卷
关键词:
FUNCTIONALIZED GRAPHENE;
GRAPHITE OXIDE;
POLYHYDROXYOCTANOATE;
BIOSYNTHESIS;
D O I:
暂无
中图分类号:
Q5 [生物化学];
Q7 [分子生物学];
学科分类号:
071010 ;
081704 ;
摘要:
Polyhydroxyalkanoates are a popular class of bioplastics valued for their rapid biodegradadion, biocompatibility, and renewable feedstocks. While there are already a few commercial applications for these biopolymers, a greater diversity of properties is needed to compete with petroleum based polymers. In this chapter, we report the synthesis and characterization of polyhdroxyoctanoate and its nanocomposite with thermally reduced graphene. The results indicate the incorporation of graphene into the PHO matrix leads to a small upshift in the glass transition, enhance the thermal stability, and similar to 600% increase in modulus. Electrical percolation between 0.5 and 1 vol.% TRG was obtained.
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页码:199 / 209
页数:11
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