A comparative study on metal organic frameworks for indoor environment application: Adsorption evaluation

被引：79
|
作者：
Bahri, Mitra [1 ]
Haghighat, Fariborz [1 ]
Kazemian, Hossein [2 ,3 ]
Rohani, Sohrab [2 ]
机构：
[1] Concordia Univ, Dept Bldg Civil & Environm Engn, Montreal, PQ, Canada
[2] Univ Western Ontario, Dept Chem & Biochem Engn, London, ON, Canada
[3] Univ British Columbia, Coll Sci & Management, Prince George, BC, Canada
来源：
CHEMICAL ENGINEERING JOURNAL | 2017年 / 313卷
关键词：
Adsorption; MIL-101; MIL-53; CPM-5; Volatile organic compound; Relative humidity; MICROWAVE SYNTHESIS; WATER-VAPOR; AIR; MIL-101; PERFORMANCE; REMOVAL; DESIGN; IMPACT; GASES; SELECTIVITY;
D O I：
10.1016/j.cej.2016.10.004
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
In this study, three metal organic frameworks (MOFs), MIL-101, MIL-53 and CPM-5 are synthesized and characterized. Adsorption isotherms and breakthrough behaviors of these MOFs are studied for two Volatile organic compounds: toluene and isobutanol. Also, the effect of the presence of relative humidity on the adsorption capacity of one (1) ppm toluene and isobutanol on each MOF is investigated. Results demonstrate a superior capacity of MIL-101 for adsorption of these organic compounds in dry air. The presence of relative humidity (30%), however, decreases this adsorption capacity by 80%. MIL-53 shows the highest adsorption capacity of toluene and isobutanol at this level of humidity, while CPM-5 shows the least adsorption capacity for both toluene and isobutanol at both dry and humid air. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码：711 / 723
页数：13
相关论文
共 50 条
  • [21] Enhanced Methane Adsorption in Catenated Metal-organic Frameworks: A Molecular Simulation Study
    Xue Chunyu
    Zhou Zi'e
    Yang Qingyuan
    Zhong Chongli
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2009, 17 (04) : 580 - 584
  • [22] Adsorption of methane in heterometallic metal-organic frameworks with anions: a molecular simulation study
    Liu, Dahuan
    Yang, Qingyuan
    Zhong, Chongli
    MOLECULAR SIMULATION, 2009, 35 (03) : 213 - 219
  • [23] Systematic evaluation of water adsorption in isoreticular UiO-type metal-organic frameworks
    Lu, Feng-Fan
    Gu, Xiao-Wen
    Wu, Enyu
    Li, Bin
    Qian, Guodong
    JOURNAL OF MATERIALS CHEMISTRY A, 2023, 11 (03) : 1246 - 1255
  • [24] Experimental study on water vapor sorption performance of metal organic frameworks and their application potential for indoor air dehumidification
    Huang, Honghao
    Nie, Jinzhe
    He, Fuqun
    INTERNATIONAL JOURNAL OF REFRIGERATION, 2024, 168 : 51 - 58
  • [25] Application of metal-organic frameworks in the purification of indoor hexanal: Experiments and DFT calculations
    Zhang, Ding-Chao
    Liu, JunJie
    Wang, Cong
    Liu, Yong
    Wang, Jia-Hua
    Han, Xu
    BUILDING AND ENVIRONMENT, 2020, 182
  • [26] Metal-organic frameworks and their composites for the adsorption and sensing of phosphate
    Moumen, Elmehdi
    Bazzi, Loubna
    El Hankari, Samir
    COORDINATION CHEMISTRY REVIEWS, 2022, 454
  • [27] Adsorption of uranium (VI) by metal-organic frameworks and covalent-organic frameworks from water
    Mei, Douchao
    Liu, Lijia
    Yan, Bing
    COORDINATION CHEMISTRY REVIEWS, 2023, 475
  • [28] Denitrogenation through Adsorption to Sulfonated Metal-Organic Frameworks
    Wang Zhao-Yang
    Li Gang
    Sun Zhi-Guo
    ACTA PHYSICO-CHIMICA SINICA, 2013, 29 (11) : 2422 - 2428
  • [29] A Series of Metal-Organic Frameworks for Adsorption of Halogenated Volatile Organic Compounds
    Nguyen, Phuong T. K.
    Tran, Y. B. N.
    CHEMISTRYSELECT, 2022, 7 (45):
  • [30] An experimental and simulation study of binary adsorption in metal-organic frameworks
    Yang, Ying
    Sitprasert, Chatcharin
    Rufford, Thomas E.
    Ge, Lei
    Shukla, Pradeep
    Wang, Shaobin
    Rudolph, Victor
    Zhu, Zhonghua
    SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 146 : 136 - 142
12345