Tunable Catalysts for Solvent-Free Biphasic Systems: Pickering Interfacial Catalysts over Amphiphilic Silica Nanoparticles

被引：145

作者：

Zhou, Wen-Juan ^{[1
,2
]}

Fang, Lin ^{[1
]}

Fan, Zhaoyu ^{[1
]}

Albela, Belen ^{[2
]}

Bonneviot, Laurent ^{[2
]}

De Campo, Floryan ^{[1
]}

Pera-Titus, Marc ^{[1
]}

Clacens, Jean-Marc ^{[1
]}

机构：

[1] Solvay, E2P2L, UMI CNRS 3464, Shanghai 201108, Peoples R China

[2] Ecole Normale Super Lyon, Lab Chim, UMR CNRS 5182, F-69364 Lyon, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 13期

关键词：

ENZYME CATALYSIS; EMULSIONS; OXIDATION; BIOMASS; CARBON;

D O I：

10.1021/ja501019n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stabilization of oil/oil Pickering emulsions using robust and recyclable catalytic amphiphilic silica nanoparticles bearing alkyl and propylsulfonic acid groups allows fast and efficient solvent-free acetalization of immiscible long-chain fatty aldehydes with ethylene glycol.

引用

页码：4869 / 4872

页数：4

共 37 条

[1] Bimetallic catalysts for upgrading of biomass to fuels and chemicals [J].

Alonso, David Martin ;

Wettstein, Stephanie G. ;

Dumesic, James A. .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (24) :8075-8098

[2]

Aveyard R., 2003, ADV COLLOID INTERFAC, V100-102, P503

[3] Particles as surfactants - similarities and differences [J].

Binks, BP .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41

[4] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[5]

Chan T. H., 1983, SYNTHESIS-STUTTGART, V3, P203

[6] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[7] Solid Nanoparticles that Catalyze Biofuel Upgrade Reactions at the Water/Oil Interface [J].

Crossley, Steven ;

Faria, Jimmy ;

Shen, Min ;

Resasco, Daniel E. .

SCIENCE, 2010, 327 (5961) :68-72

[8] Amphiphilic Nanohybrid Catalysts for Reactions at the Water/Oil Interface in Subsurface Reservoirs [J].

Drexler, Santiago ;

Faria, Jimmy ;

Ruiz, M. Pilar ;

Harwell, Jeffrey H. ;

Resasco, Daniel E. .

ENERGY & FUELS, 2012, 26 (04) :2231-2241

[9]

Fan Z., 2014, J COLLOID INTERF SCI, DOI [10.1016/j.jcis.2013.11.047, DOI 10.1016/NCIS.2013.11.047]

[10] Phase-Selective Catalysis in Emulsions Stabilized by Janus Silica-Nanoparticles [J].

Faria, Jimmy ;

Ruiz, M. Pilar ;

Resasco, Daniel E. .

ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (14-15) :2359-2364

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