Synthesis dibromo substituted BOPHY dye for the singlet oxygen generation

被引：23

作者：

Cui, Tian-Fang ^{[1
]}

Zhang, Jing ^{[1
]}

Jiang, Xin-Doug ^{[1
]}

Su, Ya-Jun ^{[1
]}

Sun, Chang-Liang ^{[2
]}

Zhao, Jiu-Li ^{[1
]}

机构：

[1] Shenyang Univ Chem Technol, Coll Appl Chem, Key Lab Rare Earth Chem & Applying Liaoning Prov, Shenyang 110142, Peoples R China

[2] Shenyang Univ Chem Technol, Ctr Phys & Chem Test, Shenyang 110142, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2016年 / 27卷 / 02期

关键词：

BOPHY; Singlet oxygen; Photosensitizer; Photophysical property; DFT; FLUORESCENCE QUANTUM YIELDS; PHOTODYNAMIC THERAPY; BASIC PRINCIPLES; BODIPY DYES; PHOTOSENSITIZERS; ENERGY; DIPYRROMETHENE; PORPHYRIN; EFFICIENT; DESIGN;

D O I：

10.1016/j.cclet.2015.11.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dibromo substituted BOPHY derivative (2) was prepared and found to exhibit photo-sensitization capability. Rapid oxidation of 80% DPBF at the first 6 min was observed suggesting that 2 is a superior photo-sensitizer than methylene blue. The HOMO-LUMO band gap for the lowest energy absorption bands of the BOPHY 1 is smaller than that of PS 2, which is in good agreement with the red shift in the absorption observed between 1 and 2. (c) 2015 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：190 / 194

页数：5

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