Cavity-Assembled Porous Solids (CAPSs) for Nanospace-Specific Functions

被引：33

作者：

Tashiro, Shohei ^{[1
]}

Shionoya, Mitsuhiko ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2014年 / 87卷 / 06期

基金：

日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; KINETIC-DATA; SUPRAMOLECULAR ASSEMBLIES; MACROCYCLE INTERACTION; CYCLIC POLYETHERS; COORDINATION; COMPLEXES; CRYSTALS; CYCLOTRIVERATRYLENE;

D O I：

10.1246/bcsj.20140007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous crystals such as metal-organic framework (MOF), porous coordination polymer (PCP), and porous organic crystals have shown promise as solid materials in terms of their great potentials for catalysis, separation and refinement techniques, environmental protection, nanoengineering, and pharmaceutical applications. Here we discuss cavity-assembled porous solids (CAPSs) formed as the result of self-assembly of macrocycles or cage compounds possessing well-defined binding cavities for guest molecules. In addition to conventional macrocycles such as cyclodextrin, crown ether, cucurbituril, calixarene, cyclotriveratrylene, pillararene, and organic cages, we have recently reported a novel crystalline nanochannel (metal-macrocycle framework: MMF) composed of macrocyclic trinuclear Pd-II complexes with tris(o-phenylenediamine)cyclophane. This account focuses on how cavities with guest-binding capability assemble to form porous structures taking recent examples.

引用

页码：643 / 654

页数：12

共 129 条

[1] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].

Abrahams, BF ;

Batten, SR ;

Hamit, H ;

Hoskins, BF ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1690-1692

[2] Group 1 coordination chains and hexagonal networks of host cyclotriveratrylene with halogenated monocarbaborane anions [J].

Ahmad, R ;

Franken, A ;

Kennedy, JD ;

Hardie, ML .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (09) :2190-2198

[3]

[Anonymous], 2009, SUPRAMOL CHEM

[4] Chemically Responsive Supramolecular Structural Change of Pillar[5]arene Nanotubes [J].

Aoki, Takamichi ;

Ogoshi, Tomoki ;

Yamagishi, Tada-aki .

CHEMISTRY LETTERS, 2011, 40 (08) :795-797

[5] Pd(II)- and Pt(II)-linked tetranuclear complexes as assembly units for higher ordered structures [J].

Aoyagi, M ;

Biradha, K ;

Fujita, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (12) :2603-2606

[6] A new type of material for the recovery of hydrogen from gas mixtures [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950

[7] Guest transport in a nonporous organic solid via dynamic van der Waals cooperativity [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A ;

Schottel, BL .

SCIENCE, 2002, 298 (5595) :1000-1002

[8] Storage of methane and freon by interstitial van der Waals confinement [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

SCIENCE, 2002, 296 (5577) :2367-2369

[9] Metal sulfonatocalix[4,5]arene complexes: bi-layers, capsules, spheres, tubular arrays and beyond [J].

Atwood, JL ;

Barbour, LJ ;

Hardie, MJ ;

Raston, CL .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :3-32

[10] Highly symmetric columnar channels in metal-free cucurbit[n] uril hydrate crystals (n = 6, 8) [J].

Bardelang, David ;

Udachin, Konstantin A. ;

Leek, Donald M. ;

Ripmeester, John A. .

CRYSTENGCOMM, 2007, 9 (11) :973-975

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