Nanostructure Fe-Co-B/bacterial cellulose based carbon nanofibers: An extremely efficient electrocatalyst toward oxygen evolution reaction

被引:15
作者
Yang, Peilin [1 ]
Li, Enmin [1 ]
Xiao, Feng [1 ]
Zhou, Pengcheng [1 ]
Wang, Yuan [1 ]
Tang, Weishan [1 ]
He, Ping [1 ,2 ]
Jia, Bin [3 ]
机构
[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China
[2] Southwest Univ Sci & Technol, Int Sci & Technol Cooperat Lab Micro Nanoparticle, Mianyang 621010, Sichuan, Peoples R China
[3] Southwest Univ Sci & Technol, Key Lab Shock & Vibrat Engn Mat & Struct Sichuan, Mianyang 621010, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
Water splitting; Oxygen evolution reaction; Electrocatalyst; Fe-Co-B; Bacterial cellulose; Carbon nanofiber; ZEOLITIC IMIDAZOLATE FRAMEWORKS; BACTERIAL CELLULOSE; BIFUNCTIONAL ELECTROCATALYST; NANOSHEETS; CATALYST; REDUCTION; IRON;
D O I
10.1016/j.ijhydene.2022.02.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is very crucial to design and prepare environmentally friendly, efficient and sustainable oxygen evolution reaction (OER) catalysts for water splitting reaction. In this work, a series of Fe-Co-B nanosheets with different molar ratio of Fe/Co precursor have been recombined with bacterial cellulose based carbon nanofiber (BCCNF) through simple electroless deposition method at room temperature. It is indicated that, when the Fe/Co molar ratio is 1:3, Fe-Co-B/BCCNF exhibits an excellent catalytic property with overpotential of only 160 mV at 10 mA cm(-2). Furthermore, it displays a prominent electrochemical stability, even over 30 h of OER process under alkaline condition. The strategy of designing 3D nanostructure and constructing metal-boride-based catalyst for OER provides valuable insights into efficient oxygen evolution.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:12953 / 12963
页数:11
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