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Nanostructure Fe-Co-B/bacterial cellulose based carbon nanofibers: An extremely efficient electrocatalyst toward oxygen evolution reaction
被引:15
|作者:
Yang, Peilin
[1
]
Li, Enmin
[1
]
Xiao, Feng
[1
]
Zhou, Pengcheng
[1
]
Wang, Yuan
[1
]
Tang, Weishan
[1
]
He, Ping
[1
,2
]
Jia, Bin
[3
]
机构:
[1] Southwest Univ Sci & Technol, Sch Mat Sci & Engn, Mianyang 621010, Sichuan, Peoples R China
[2] Southwest Univ Sci & Technol, Int Sci & Technol Cooperat Lab Micro Nanoparticle, Mianyang 621010, Sichuan, Peoples R China
[3] Southwest Univ Sci & Technol, Key Lab Shock & Vibrat Engn Mat & Struct Sichuan, Mianyang 621010, Sichuan, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Water splitting;
Oxygen evolution reaction;
Electrocatalyst;
Fe-Co-B;
Bacterial cellulose;
Carbon nanofiber;
ZEOLITIC IMIDAZOLATE FRAMEWORKS;
BACTERIAL CELLULOSE;
BIFUNCTIONAL ELECTROCATALYST;
NANOSHEETS;
CATALYST;
REDUCTION;
IRON;
D O I:
10.1016/j.ijhydene.2022.02.053
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
It is very crucial to design and prepare environmentally friendly, efficient and sustainable oxygen evolution reaction (OER) catalysts for water splitting reaction. In this work, a series of Fe-Co-B nanosheets with different molar ratio of Fe/Co precursor have been recombined with bacterial cellulose based carbon nanofiber (BCCNF) through simple electroless deposition method at room temperature. It is indicated that, when the Fe/Co molar ratio is 1:3, Fe-Co-B/BCCNF exhibits an excellent catalytic property with overpotential of only 160 mV at 10 mA cm(-2). Furthermore, it displays a prominent electrochemical stability, even over 30 h of OER process under alkaline condition. The strategy of designing 3D nanostructure and constructing metal-boride-based catalyst for OER provides valuable insights into efficient oxygen evolution.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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页码:12953 / 12963
页数:11
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