Gold-catalyzed transannular [4+3] cycloaddition reactions

被引：37

作者：

Gung, Benjamin W. ^{[1
]}

Craft, Derek T. ^{[1
]}

机构：

[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 22期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/j.tetlet.2009.03.138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a catalytic amount of Au(I) and Ag(I) salts, the 14-membered furanophane II with an allene function located across the ring undergoes both a transannular [4+3] and [4+2] cycloaddition. Secondary rearrangement Products Containing a tricyclic ring system were isolated when the catalyst was PtCl2. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2685 / 2687

页数：3

共 6 条

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