Probing the Inner Space of Salt-Bridged Calix[5]arene Capsules

被引：29

作者：

Brancatelli, Giovanna ^{[1
]}

Gattuso, Giuseppe ^{[2
]}

Geremia, Silvano ^{[1
]}

Notti, Anna ^{[2
]}

Pappalardo, Sebastiano ^{[3
]}

Parisi, Melchiorre F. ^{[2
]}

Pisagatti, Ilenia ^{[2
]}

机构：

[1] Univ Trieste, Ctr Eccellenza Biocristallog, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy

[2] Univ Messina, Dipartimento Sci Chim, I-98166 Messina, Italy

[3] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 09期

关键词：

CYLINDRICAL CAPSULE; MOLECULAR CAPSULE; ENCAPSULATION; RECOGNITION; STATE; TETRAUREA; DYNAMICS; ALKANES; DRIVEN;

D O I：

10.1021/ol500673n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A combined DOSY and XRD study indicates that a carboxylcalix[5]arene receptor is able to encapsulate alpha,omega-diamines of appropriate length by means of a proton-transfer-mediated recognition process followed by salt-bridge-assisted bis-endo-complexation.

引用

页码：2354 / 2357

页数：4

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