Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide

被引:91
作者
He, Ling-Feng [1 ]
Roman, Paul [1 ]
Leng, Bin [1 ]
Sridharan, Kumar [1 ]
Anderson, Mark [1 ]
Allen, Todd R. [1 ]
机构
[1] Univ Wisconsin Madison, Dept Engn Phys, Madison, WI 53706 USA
关键词
Stainless steels; SEM; STEM; High temperature corrosion; Oxidation; Carburization; STAINLESS-STEELS; DEGREES-C; OXIDATION; ALLOYS; MECHANISM; KINETICS; NIOBIUM;
D O I
10.1016/j.corsci.2013.12.023
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Microstructure characterization of corrosion behavior of an alumina forming austenitic (AFA) steel exposed to supercritical carbon dioxide was conducted at 450-650 degrees C and 20 MPa. At low temperature and short exposure times, the oxidation kinetics were parabolic and the oxide scales were mainly composed of protective and continuous Al2O3 and (Cr, Mn)-rich oxide layers. As the temperature and exposure time increased, the AFA steel gradually suffered breakaway oxidation and its oxide scales showed a multilayer structure mainly composed of Fe3O4, (Cr, Fe)(3)O-4, NiFe/FeCr2O4/Cr2O3/Al2O3, FeCr2O4/Al2O3, and NiFe/Cr2O3/Al2O3, in sequence. The corrosion mechanism based on the microstructure evolution is discussed in detail. Published by Elsevier Ltd.
引用
收藏
页码:67 / 76
页数:10
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