Copper-mediated oxygenation of flavonolate in the presence of a tridentate N-ligand.: Synthesis and crystal structures of [Cu(fla)(idpaH)]ClO4 and [Cu(idpaH)(O-bs)]ClO4, [fla = flavonolate, idpaH=3,3′-iminobis(N,N-dimethylpropylamine), O-bs = O-benzoylsalicylate]

被引：28

作者：

Balogh-Hergovich, É

Kaizer, J

Speier, G ^{[1
]}

Huttner, G

Zsolnai, L

机构：

[1] Univ Veszprem, Dept Organ Chem, H-8201 Veszprem, Hungary

[2] Hungarian Acad Sci, Res Grp Petrochem, H-8201 Veszprem, Hungary

[3] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

INORGANICA CHIMICA ACTA | 2000年 / 304卷 / 01期

基金：

匈牙利科学研究基金会;

关键词：

crystal structures; copper; flavonolate complexes; salicylate complexes;

D O I：

10.1016/S0020-1693(00)00071-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Cu(fla)(idpaH)] ClO4 (4) and [Cu(idpaH)(O-bs)] ClO4 (5) (fla = flavonolate, idpaH = 3,3'-iminobis(N, N-dimethylpropylamine), O-bs = O-benzoylsalicylate) have been synthesised and characterised. Complex 5 can be obtained also by the oxygenation of 4 and concomitant CO release. The structures of the compounds have been determined by X-ray diffraction. Complex 4 exhibits distorted trigonal-bipyramidal geometry around the copper(II) ion while complex 5 is distorted square-pyramidal. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：72 / 77

页数：6

共 32 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].