In situ hydrogenation of terminal halogen in poly(methyl methacrylate) by ruthenium-catalyzed living radical polymerization: Direct transformation of "polymerization catalyst" into "hydrogenation catalyst"

An in situ, selective, and quantitative hydrogenation of the terminal chlorine (α-haloester) in living PMMA-Cl into PMMA-H was achieved via direct transformation of a "polymerization catalyst" into a "hydrogenation catalyst" in the Ru(II)-catalyzed living radical polymerization, where the polymerization mixture of MMA was directly treated in situ with K2CO3 as a base and 2-propanol as a hydrogen donor. The reaction terminated the polymerization and, more importantly, the terminal chlorine was quantitatively hydrogenated, as confirmed by SEC, 1H NMR, and MALDI-TOF MS. Copyright © 2006 American Chemical Society.