Transition-metal-catalyzed regioselective aroyl- and trifluoro-acetylthiolation of alkynes using thioesters

被引：38
作者：
Minami, Yasunori [1 ]
Kuniyasu, Hitoshi [1 ]
Miyafuji, Kiyoshi [1 ]
Kambe, Nobuaki [1 ]
机构：
[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 21期
关键词：
ADDITION-REACTIONS; COMPLEXES; RHODIUM; INSERTION; PLATINUM; SULFIDES; BOND; HYDROSILYLATION; DECARBONYLATION; 1,3-DIENES;
D O I：
10.1039/b900492k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford beta-SR substituted enone derivatives; the choice of catalyst (Pd(dba)(2)-dppe) and the introduction of a CF3 group into the thioesters are the key to achieving the transformation.
引用
收藏
页码：3080 / 3082
页数：3
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