Oxidative addition of (PhSe)2 and (FcSe)2 to zerovalent palladium and platinum trialkylphosphine complexes (Fc = ferrocenyl, [Fe(η5-C5H5)(η5-C5H4)])

被引：23

作者：

Morley, Christopher P.

Webster, Christopher A.

Di Vaira, Massimo

机构：

[1] Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales

[2] Univ Florence, Dipartimento Chim, I-50019 Florence, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 20期

关键词：

ferrocene; selenium; palladium; platinum;

D O I：

10.1016/j.jorganchem.2006.06.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Room temperature reaction of [Pd-2(dba)(3)]PR3 or [Pt(C2H4)(PR3)(2)] (dba = dibenzylideneacetone; R = Et, Bu) with the diselenides (R'Se)(2) (R' = Ph, Fc) yielded the oxidative addition products trans-[M(SeR')(2)(PR3)(2)] (M = Pd, Pt). These have been characterised by multinuclear NMR and UV-Vis spectroscopy, mass spectrometry, and, in the cases of trans-[Pt(SePh)(2)(PR3)(2)] (R = Et, Bu) and trans- [Pt(SeFc)(2)(PBu3)(2)], also by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：4244 / 4249

页数：6

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