Proton-fueled, reversible assembly of gold nanoparticles by controlled triplex formation

被引：43
作者：
Jung, Young Hwan
Lee, Kyung-Bok
Kim, Yang-Gyun
Choi, Insung S. [1 ]
机构：
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Ctr Mol Design & Synth, Taejon 305701, South Korea
[4] KBSI, Glycom Team, Taejon 305333, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 36期
关键词：
DNA structures; gold; nanoparticles; protonation; self-assembly;
D O I：
10.1002/anie.200601089
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Fueled up: The protonation of the imino group of cytosines in double-stranded DNA, which is required for the formation of a triplex, can be used to guide the assembly/disassembly of DNA-conjugated gold nanoparticles. The reversible switching of the nanoparticles is demonstrated by repeated cycling of pH between 5.0 and 6.5 with the proton as a fuel (see picture). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5960 / 5963
页数：4
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