Aerogels from quaternary ammonium-functionalized cellulose nanofibers for rapid removal of Cr(VI) from water

被引:83
作者
He, Xu [1 ]
Cheng, Long [1 ]
Wang, Yaru [1 ]
Zhao, Jiangqi [1 ]
Zhang, Wei [1 ]
Lu, Canhui [1 ]
机构
[1] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
基金
中国国家自然科学基金;
关键词
Adsorption; Aerogel; Cellulose nanofibers; Heavy metal pollution; Water treatment; MULTIWALLED CARBON NANOTUBES; AQUEOUS-SOLUTION; HEAVY-METALS; ADSORPTION; CHROMIUM; EXTRACTION; VI;
D O I
10.1016/j.carbpol.2014.05.020
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An efficient heavy metal adsorbent from quaternary ammonium-functionalized cellulose nanofiber aerogels was successfully developed. The highly porous aerogel could well retain its large specific surface area, which allowed rapid and effective removal of Cr(VI) from contaminated water. The aerogel adsorbent became mechanically robust after chemical crosslinking. It could be easily separated from water after adsorption without complicated centrifugation or filtration process. With only 1 g of aerogel, more than 99% of Cr(VI) in 1 L of 1 mg/L solution could be removed in 50 min. Besides, the aerogel also exhibited excellent reusability. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:683 / 687
页数:5
相关论文
共 28 条
[1]   Adsorption of chromium (VI) ion from aqueous solution by succinylated mercerized cellulose functionalized with quaternary ammonium groups [J].
Alves Gurgel, Leandro Vinicius ;
Perin de Melo, Julio Cesar ;
de Lena, Jorge Carvalho ;
Gil, Laurent Frederic .
BIORESOURCE TECHNOLOGY, 2009, 100 (13) :3214-3220
[2]   Removal of Cr(VI) from aqueous solution using Bael fruit (Aegle marmelos correa) shell as an adsorbent [J].
Anandkumar, J. ;
Mandal, B. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 168 (2-3) :633-640
[3]   Fe3O4/cyclodextrin polymer nanocomposites for selective heavy metals removal from industrial wastewater [J].
Badruddoza, Abu Zayed M. ;
Shawon, Zayed Bin Zakir ;
Daniel, Tay Wei Jin ;
Hidajat, Kus ;
Uddin, Mohammad Shahab .
CARBOHYDRATE POLYMERS, 2013, 91 (01) :322-332
[4]   Cr(VI) sorption behavior from aqueous solutions onto polymeric microcapsules containing a long-chain quaternary ammonium salt: Kinetics and thermodynamics analysis [J].
Barassi, Giancarlo ;
Valdes, Andrea ;
Araneda, Claudio ;
Basualto, Carlos ;
Sapag, Jaime ;
Tapia, Cristian ;
Valenzuela, Fernando .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 172 (01) :262-268
[5]   Surface-functionalized polymer nanoparticles for selective sequestering of heavy metals [J].
Bell, CA ;
Smith, SV ;
Whittaker, MR ;
Whittaker, AK ;
Gahan, LR ;
Monteiro, MJ .
ADVANCED MATERIALS, 2006, 18 (05) :582-+
[6]   Foreword [J].
Chen, Sinn-wen ;
Chada, Srinivas ;
Chen, Chih-ming ;
Flandorfer, Hans ;
Lindsay Greer, A. ;
Lee, Jae-Ho ;
Zeng, Kejun ;
Suganuma, Katsuaki .
JOURNAL OF ELECTRONIC MATERIALS, 2009, 38 (01) :1-1
[7]   Removal of Cr(VI) from aqueous solution by two Lewatit-anion exchange resins [J].
Gode, F ;
Pehlivan, E .
JOURNAL OF HAZARDOUS MATERIALS, 2005, 119 (1-3) :175-182
[8]   Uniaxially Aligned Electrospun All-Cellulose Nanocomposite Nanofibers Reinforced with Cellulose Nanocrystals: Scaffold for Tissue Engineering [J].
He, Xu ;
Xiao, Qiang ;
Lu, Canhui ;
Wang, Yaru ;
Zhang, Xiaofang ;
Zhao, Jiangqi ;
Zhang, Wei ;
Zhang, Ximu ;
Deng, Yulin .
BIOMACROMOLECULES, 2014, 15 (02) :618-627
[9]   Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes [J].
Hu, Jun ;
Chen, Changlun ;
Zhu, Xiaoxiang ;
Wang, Xiangke .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 162 (2-3) :1542-1550
[10]   Preparation and Adsorption Behavior of Aminated Electrospun Polyacrylonitrile Nanofiber Mats for Heavy Metal Ion Removal [J].
Kampalanonwat, Pimolpun ;
Supaphol, Pitt .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (12) :3619-3627