Dielectric characterization of Bi3.25La0.75Ti3O12 thin films

被引:66
作者
Wu, D [1 ]
Li, AD
Ming, NB
机构
[1] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Dept Mat Sci & Technol, Nanjing 210093, Peoples R China
关键词
D O I
10.1063/1.1757631
中图分类号
O59 [应用物理学];
学科分类号
摘要
Dielectric properties of Pt/Bi3.25La0.75Ti3O12(BLaT)/Pt ferroelectric thin film capacitors were studied as functions of frequency (40-10(6) Hz) and temperature (30-590 degreesC). BLaT thin films showed a first-order para-ferroelectric transition around 400 degreesC. Pt/BLaT/Pt capacitors post-annealed in Ar exhibited broadened transition with larger losses, which was interpreted in terms of increased oxygen vacancies. Via complex impedance spectroscopy study, the conduction activation energy of the space charges was determined to be similar to1.1 eV, close to that of oxygen vacancies in perovskite materials. The impedance characteristics of Pt/BLaT/Pt were compared with those of Pt/SrBi2Ta2O9(SBT)/Pt capacitors. The impact of dielectric characteristics on fatigue resistance of BLaT films was briefly discussed in comparison with SBT films. (C) 2004 American Institute of Physics.
引用
收藏
页码:4505 / 4507
页数:3
相关论文
共 26 条
[1]   Structural and dielectric characterization of Sm2Bi2Ti3O12 ferroelectric ceramics [J].
AlvarezFregoso, O .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (03) :1387-1391
[2]   Impedance spectroscopy of SrBi2Ta2O9 and SrBi2Nb2O9 ceramics correlation with fatigue behavior [J].
Chen, TC ;
Thio, CL ;
Desu, SB .
JOURNAL OF MATERIALS RESEARCH, 1997, 12 (10) :2628-2637
[3]   Formation and characteristics of highly c-axis-oriented Bi3.25La0.75Ti3O12 thin films on SiO2/Si(100) and Pt/Ti/SiO2/Si(100) substrates [J].
Chon, U ;
Jang, HM ;
Lee, SH ;
Yi, GC .
JOURNAL OF MATERIALS RESEARCH, 2001, 16 (11) :3124-3132
[4]   Fatigue-free behavior of highly oriented Bi3.25La0.75Ti3O12 thin films grown on Pt/Ti/SiO2/Si(100) by metalorganic solution decomposition [J].
Chon, U ;
Yi, GC ;
Jang, HM .
APPLIED PHYSICS LETTERS, 2001, 78 (05) :658-660
[5]   Fatigue of Pb(Zr0.53Ti0.47)O3 ferroelectric thin films [J].
Du, XF ;
Chen, IW .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (12) :7789-7798
[6]   Dielectric properties of layered perovskite Sr1-xAxBi2Nb2O9 ferroelectrics (A=La, Ca and x=0,0.1) [J].
Forbess, MJ ;
Seraji, S ;
Wu, Y ;
Nguyen, CP ;
Cao, GZ .
APPLIED PHYSICS LETTERS, 2000, 76 (20) :2934-2936
[7]   Large remanent polarization of (Bi,Nd)4Ti3O12 epitaxial thin films grown by metalorganic chemical vapor deposition [J].
Kojima, T ;
Sakai, T ;
Watanabe, T ;
Funakubo, H ;
Saito, K ;
Osada, M .
APPLIED PHYSICS LETTERS, 2002, 80 (15) :2746-2748
[8]  
Kumar MM, 2001, J APPL PHYS, V90, P934, DOI 10.1063/1.1383267
[9]   Ferroelectric Bi3.25La0.75Ti3O12 films of uniform a-axis orientation on silicon substrates [J].
Lee, HN ;
Hesse, D ;
Zakharov, N ;
Gösele, U .
SCIENCE, 2002, 296 (5575) :2006-2009
[10]   ELECTRICAL-CONDUCTIVITY IN PZT-TYPE AND PT-TYPE PIEZOCERAMICS [J].
LEE, YY ;
WU, L ;
LIANG, CK ;
WU, TS .
FERROELECTRICS, 1993, 138 (1-4) :11-22