Asymmetric Catalysis Using Chiral, Enantiopure Disulfonimides

被引：0

作者：

van Gemmeren, Manuel ^{[1
]}

Lay, Frank ^{[1
]}

List, Benjamin ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ALDRICHIMICA ACTA | 2014年 / 47卷 / 01期

基金：

欧洲研究理事会;

关键词：

disulfonimide catalysis; asymmetric counteranion-directed catalysis (ACDC); Lewis acid organocatalysis; chiral Bronsted acid catalysis; asymmetric catalysis; DIELS-ALDER REACTION; ENANTIOSELECTIVE DIENOLATE ADDITIONS; LEWIS-BASE ACTIVATION; SILYL KETENE ACETALS; MUKAIYAMA-ALDOL; HOMOGENEOUS CATALYSIS; CARBONYL-COMPOUNDS; CRUCIAL ROLE; FREE-ENERGY; ACID;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Disulfonimides have recently emerged as powerful (pre)-catalysts, especially in Lewis acid organocatalysis. Herein, we survey the development of these catalysts, their application in asymmetric catalysis using the concept of asymmetric counteranion-directed catalysis (ACDC), and mechanistic studies that aim to elucidate the catalytic cycle and the intermediates involved.

引用

页码：3 / 13

页数：11

共 121 条

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