Detection of chemical warfare simulants by phosphorylation of a coumarin oximate

被引：134

作者：

Wallace, Karl J.

Fagbemi, Ruth I.

Folmer-Andersen, Frantz J.

Morey, Jeroni

Lynth, Vincent M.

Anslyn, Eric V. ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Illes Balears, Dept Quim, Palma de Mallorca 07122, Spain

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 37期

关键词：

D O I：

10.1039/b609861d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The detection of chemical warfare simulants is attained by the PET mechanism that gives an "off-on" fluorescent response with a half-life of approximately 50 ms upon phosphorylation of a reactive oximate functionality; the X-ray crystal structure of the oximate was also obtained and is discussed.

引用

收藏

页码：3886 / 3888

页数：3

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