Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate

被引:0
|
作者
MacNeill, Christopher M. [1 ]
Day, Cynthia S. [1 ]
Noftle, Ronald E. [1 ]
机构
[1] Wake Forest Univ, Dept Chem, Winston Salem, NC 27109 USA
基金
美国国家科学基金会;
关键词
COMPLEX;
D O I
10.1107/S1600536809011337
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Co-2(C10H2O4S3)(2)(C12H8N2)(4)]center dot 2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2',3'-d]thiophene-2,6-dicarboxylate anions. The anions act as bridges between the Co-II centers.
引用
收藏
页码:M486 / U267
页数:15
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