Growth by the heat exchanger method and characterization of neighborite, NaMgF3

被引:9
作者
Ocafrain, A [1 ]
Chaminade, JP [1 ]
Viraphong, O [1 ]
Cavagnat, R [1 ]
Couzi, M [1 ]
Pouchard, M [1 ]
机构
[1] SPECT MOL & CRISTALLINE LAB,F-33405 TALENCE,FRANCE
关键词
D O I
10.1016/0022-0248(96)00112-1
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The home-made heat exchanger method (HEM) apparatus has been adapted to the growth of NaMgF3 ingots. By unseeded crystal growth using presynthesized NaMgF3 the structure was maintained during growth. Twinning introduced by the high-temperature phase transition is observed in the crystal. Studies on the crystals, at high temperature, by optical microscopy, calorimetry and Raman scattering, show a unique phase transition, from orthorhombic (Pbnm) to cubic (Pm3m) structure, at about 770 degrees C.
引用
收藏
页码:414 / 418
页数:5
相关论文
共 10 条
[1]   POSSIBLE SPECIES OF FERROMAGNETIC, FERROELECTRIC, AND FERROELASTIC CRYSTALS [J].
AIZU, K .
PHYSICAL REVIEW B, 1970, 2 (03) :754-&
[2]  
CHAO ECT, 1961, AM MINERAL, V16, P379
[3]   NEW MEASUREMENTS OF THE EMISSION-SPECTRA OF SM2+ IN KMGF3 AND NAMGF3 CRYSTALS [J].
GACON, JC ;
GROS, A ;
BILL, H ;
WICKY, JP .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1981, 42 (07) :587-593
[4]  
LEWIS MH, 1971, AM MINERAL, V56, P1519
[5]   MELT TEXTURING OF YBA2CU3O7-X BY THE HEAT-EXCHANGER METHOD [J].
OCAFRAIN, A ;
CHAMINADE, JP ;
DORDOR, P ;
RABARDEL, L ;
POUCHARD, M .
JOURNAL DE PHYSIQUE III, 1994, 4 (11) :2131-2136
[6]   DOMAIN-WALL ORIENTATIONS IN FERROELASTICS [J].
SAPRIEL, J .
PHYSICAL REVIEW B, 1975, 12 (11) :5128-5140
[7]  
Schmid F., 1975, US patent No, Patent No. 3898051
[8]   INVESTIGATION OF THE GROWTH OF NEIGHBORITE, NAMGF3 [J].
SENGUPTA, S ;
CASSANHO, A ;
JENSSEN, HP .
JOURNAL OF CRYSTAL GROWTH, 1993, 128 (1-4) :709-713
[9]  
ZHAO Y, 1991, T AM GEOPHYS UNION, V72, P478
[10]   THERMAL-EXPANSION AND STRUCTURAL DISTORTION OF PEROVSKITE - DATA FOR NAMGF3 PEROVSKITE .1. [J].
ZHAO, YS ;
WEIDNER, DJ ;
PARISE, JB ;
COX, DE .
PHYSICS OF THE EARTH AND PLANETARY INTERIORS, 1993, 76 (1-2) :1-16