High resolution study of Q-branches in the E1Π-X1Σ+ (0,0) band of 12C16O, 13C16O, and 13C18O

被引：18
作者：
Cacciani, P
Ubachs, W
机构：
[1] Vrije Univ Amsterdam, Dept Phys & Astron, Ctr Laser, NL-1081 HV Amsterdam, Netherlands
[2] Univ Sci & Tech Lille Flandres Artois, Lab PhLAM, F-59655 Villeneuve Dascq, France
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2004年 / 225卷 / 01期
关键词：
D O I：
10.1016/j.jms.2004.02.009
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
A tunable and narrowband vacuum ultraviolet laser system near lambda = 107.5 run is used to record Doppler-free molecular beam spectra of the E(1)Pi-X(1)Sigma(+) (0, 0) band for three isotopomers of carbon monoxide. The Q branches of the E-X (0, 0) bands in (CO)-C-12-O-16, (CO)-C-13-O-16, and (CO)-C-13-O-18 are fully resolved in this study, performed at a resolution of 0.02 cm(-1) (FWHM). The newly obtained data are included in a comprehensive fitting routine with previous data to yield optimized molecular constants for the upper level. (C) 2004 Elsevier Inc. All rights reserved.
引用
收藏
页码：62 / 65
页数：4
相关论文
共 17 条
[1]  
[Anonymous], 1978, ATLAS SPECTRE ABSORP
[2]   A 2+1 REMPI STUDY OF THE E-X TRANSITION IN CO - INDIRECT PREDISSOCIATIONS IN THE E(1)PI STATE [J].
BAKER, J ;
LEMAIRE, JL ;
COURIS, S ;
VIENT, A ;
MALMASSON, D ;
ROSTAS, F .
CHEMICAL PHYSICS, 1993, 178 (1-3) :569-579
[3]   Widely usable interpolation formulae for hyperfine splittings in the 127I2 spectrum [J].
Bodermann, B. ;
Knöckel, H. ;
Tiemann, E. .
European Physical Journal D, 2002, 19 (01) :31-44
[4]   Lifetime measurements of the E 1Π, υ=0 and υ=1 states of 12C16O, 13C16O, and 13C18O [J].
Cacciani, P ;
Lynga, C ;
L'Huillier, A ;
Wahlstrom, CG ;
Ubachs, W ;
Hinnen, PC .
ASTROPHYSICAL JOURNAL, 1998, 499 (02) :L223-L226
[5]   ACCIDENTAL PREDISSOCIATION PHENOMENA IN THE E(1)PI, V=0 AND V=1 STATES OF (CO)-C-12-O-16 AND (CO)-C-13-O-16 [J].
CACCIANI, P ;
HOGERVORST, W ;
UBACHS, W .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (21) :8308-8320
[6]   Isotope dependent predissociation in the C1Σ+ ,v=0 and v=1 states of CO [J].
Cacciani, P ;
Brandi, F ;
Velchev, I ;
Lyngâ, C ;
Wahlström, CG ;
Ubachs, W .
EUROPEAN PHYSICAL JOURNAL D, 2001, 15 (01) :47-56
[7]  
Cariou J., 1980, ATLAS SPECTRE ABSORP
[8]  
EIDELSBERG M, 1990, ASTRON ASTROPHYS, V235, P472
[9]  
EIDELSBERG M, 1991, ASTRON ASTROPHYS SUP, V90, P231
[10]  
EIDELSBERG M, 1992, ASTRON ASTROPHYS, V265, P839
12