Diffusion dialysis of hydrochloric acid with their salts: Effect of co-existence metal ions

The diffusion dialysis (DD) of hydrochloric acids in presence of their different metal salts has been investigated with a two-compartment cell in the following systems: HCl + NaCl, HCl + FeCl2, HCl + NiCl2, HCl + CuCl2, HCl + ZnCl2, and HCl + AlCl3. The corresponding permeability coefficients (P) from an organic-inorganic hybrid anion exchange membrane are determined by a simple method. That is, the experimental ions concentrations in diffusate are fitted based on the mass transfer and ionic equilibrium equations, combined with an optimized procedure. The fitted P values for Cl- follow the order in the investigated concentration range: P-Cl-(total)(CuCl2)(6.1 x 10(-6) m/s) > P-Cl-(total)(FeCl2) (3.1 x 10(-6) m/s) > P-Cl-(total)(NiCl2)(2.6 x 10(-6) m/s) > P-Cl-(total)(AlCl3)(2.0 x 10(-6) m/s) > P-Cl-(total)(NaCl)(1.6 X 10(-6) m/s) > P-Cl-(total)(ZnCl2)(3.4 x 10(-7) m/s) This changing trend is then correlated with the metal-acid complexes formation as well as the physic-chemical properties of metal ions: Cu, Fe, Ni can promote the transport of chloride ions much more than Al and Na due to their positive or neutral complexes formation with Cl-, whereas, Zn shows apparent hindrance effect to DD at its high concentration because of the dissociation equilibrium of large amount of its negative complexes within the membrane. And compared with Al, Na shows less influence to HCl transport because of its lower valence. The complexes formations between metal ions with Cl- contribute much to DD effect, as reflected well by the P value. Our work here investigates and compares the permeability of ions in the systems with different metal salts through a simple and easy method. Therefore, the results and findings can provide clues for further DD developments and applications in metal industries. (C) 2013 Elsevier B.V. All rights reserved.