Homeotropic Alignment of Dendritic Columnar Liquid Crystal Induced by Hydrogen-Bonded Triphenylene Core Bearing Fluoroalkyl Chains

被引：8
作者：
Ishihara, Shinsuke [1 ,2 ]
Furuki, Yusuke [2 ]
Hill, Jonathan P. [3 ]
Ariga, Katsuhiko [3 ]
Takeoka, Shinji [4 ]
机构：
[1] Natl Inst Mat Sci NIMS, Int Ctr Young Scientists ICYS, World Premier Int WPI, Res Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[2] Waseda Univ, Grad Sch Adv Sci & Engn, Dept Appl Chem, Shinjyuku Ku, Tokyo 1698555, Japan
[3] Natl Inst Mat Sci NIMS, Res Ctr Mat Nanoarchitecton MANA, World Premier Int WPI, Tsukuba, Ibaraki 3050044, Japan
[4] Waseda Univ TWIns, Grad Sch Adv Sci & Engn, Dept Life Sci & Med Biosci, Shinjyuku Ku, Tokyo 1628480, Japan
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2014年 / 14卷 / 07期
基金：
日本科学技术振兴机构;
关键词：
Liquid Crystal; Triphenylene; Dendron; Homeotropic Alignment; Hydrogen-Bond; MONODENDRONS; ASSEMBLIES; CHIRALITY; FILMS;
D O I：
10.1166/jnn.2014.8684
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 1:3 molar complex of the fluoroalkyl side chain-substituted 2,6,10-tris-carboxymethoxy-3,7,11-tris(4,4,5,5,6,6,7,7,7-nonafluoroheptyloxy) triphenylene (TPF4) with the second generation dendron 3,5-bis(3,4-bis-dodecyloxybenzyloxy)-N-pyridin-4-yl-benzamide (DN) assembled through complementary hydrogen bonding to form a supramolecular columnar liquid crystal, which exhibited homeotropic alignment when sandwiched between octadecyltrichlorosilane (OTS)-coated or indium tin oxide (ITO)-coated glass plates due to specific interactions between the fluoroalkyl side chains and the substrates.
引用
收藏
页码：5130 / 5137
页数：8
相关论文
共 46 条
[1]   TRANSIENT PHOTOCONDUCTIVITY IN A DISCOTIC LIQUID-CRYSTAL [J].
ADAM, D ;
CLOSS, F ;
FREY, T ;
FUNHOFF, D ;
HAARER, D ;
RINGSDORF, H ;
SCHUHMACHER, P ;
SIEMENSMEYER, K .
PHYSICAL REVIEW LETTERS, 1993, 70 (04) :457-460
[2]   Porphyrin capped with calix[4]arene derivative via hydrogen bonds [J].
Arai, S ;
Ohkawa, H ;
Ishihara, S ;
Shibue, T ;
Takeoka, S ;
Nishide, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2005, 78 (11) :2007-2013
[3]   Stability of porphyrin-calix[4]arene complexes analyzed by electrospray ionization mass spectrometry [J].
Arai, S ;
Ishihara, S ;
Takeoka, S ;
Ohkawa, H ;
Shibue, T ;
Nishide, H .
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2004, 18 (18) :2065-2068
[4]  
Ariga K., 2013, CHEM MATER, DOI [10.1021/cm401999f, DOI 10.1021/CM401999F)]
[5]   Challenges and breakthroughs in recent research on self-assembly [J].
Ariga, Katsuhiko ;
Hill, Jonathan P. ;
Lee, Michael V. ;
Vinu, Ajayan ;
Charvet, Richard ;
Acharya, Somobrata .
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2008, 9 (01)
[6]   Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application [J].
Ariga, Katsuhiko ;
Hill, Jonathan P. ;
Ji, Qingmin .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (19) :2319-2340
[7]   Nanoarchitectonics for Mesoporous Materials [J].
Ariga, Katsuhiko ;
Vinu, Ajayan ;
Yamauchi, Yusuke ;
Ji, Qingmin ;
Hill, Jonathan P. .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2012, 85 (01) :1-32
[8]   Materials nanoarchitectonics for environmental remediation and sensing [J].
Ariga, Katsuhiko ;
Ishihara, Shinsuke ;
Abe, Hideki ;
Li, Mao ;
Hill, Jonathan P. .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (06) :2369-2377
[9]   Operation of micro and molecular machines: a new concept with its origins in interface science [J].
Ariga, Katsuhiko ;
Ishihara, Shinsuke ;
Izawa, Hironori ;
Xia, Hong ;
Hill, Jonathan P. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (11) :4802-4811
[10]   Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts [J].
Ariga, Katsuhiko ;
Richards, Gary J. ;
Ishihara, Shinsuke ;
Izawa, Hironori ;
Hill, Jonathan P. .
SENSORS, 2010, 10 (07) :6796-6820
12345