Synthesis, characterization and electrochemistry of 1-phenoxypropan-2-yloxy substituted phthalocyanines

被引：7

作者：

Akyuz, Duygu ^{[1
]}

Demirbas, Umit ^{[2
]}

Akcay, Hakki Turker ^{[3
]}

机构：

[1] Gebze Tech Univ, Fac Sci, Dept Chem, Kocaeli, Turkey

[2] Karadeniz Tech Univ, Fac Sci, Dept Chem, Trabzon, Turkey

[3] Recep Tayyip Erdogan Univ, Fac Arts & Sci, Dept Chem, Rize, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2020年 / 923卷

关键词：

Phthalonitrile; Phthalocyanine; Electrochemistry; Spectroelectrochemistry; Electrocolorimetry; SPECTROELECTROCHEMICAL PROPERTIES; METAL-FREE; PHOTOCHEMICAL PROPERTIES; COBALT; METALLOPHTHALOCYANINES; ZINC(II); BEARING; COPPER(II); COMPLEXES; ZN(II);

D O I：

10.1016/j.jorganchem.2020.121455

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4-(1-phenoxypropan-2-yloxy)phthalonitrile (3) and peripherally tetra 1-phenoxypropan-2-yloxy substituted zinc(II) (4), cobalt(II) (5) and copper(II) (6) phthalocyanine were prepared. Structural characterization of novel complexes was performed by spectrophotometric measurements. The determination of the redox active or redox inactive metal center effect on the electrochemistry, in-situ spectroelectrochemisty and electrocolorimetry of compounds were performed in dimethylformamide. The redox properties and mechanisms were examined by electrochemical measurements. The peripherally tetra substituted cobalt(II) phthalocyanine (5) showed both metal and ligand-based redox processes, while zinc(II) (4) and cobalt(II) phthalocyanines only displayed ligand-based redox processes. These results were confirmed by electrochemical and in-situ spectroelectrochemical measurements. Moreover, the semiconducting nature of the compounds were illuminated via electrochemical measurements. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：8

共 42 条

[1] Synthesis, electrochemistry and electrocatalytic activity of cobalt phthalocyanine complexes - Effects of substituents for oxygen reduction reaction [J].