Activation of C2-C4 alkanes over acid and bifunctional zeolite catalysts

被引：240
作者：
Caeiro, G.
Carvalho, R. H.
Wang, X.
Lemos, M. A. N. D. A.
Lemos, F.
Guisnet, M.
Ribeiro, F. Ramoa
机构：
[1] Inst Super Tecn, Ctr Engn Biol & Quim, P-1049001 Lisbon, Portugal
[2] Univ Poitiers, UMR 6503, Catalyse Chim Organ Lab, F-86022 Poitiers, France
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 255卷 / 1-2期
关键词：
C-2-C-4; alkanes; activation; aromatization; butane isomerization; dehydroisomerization; isobutane-butene alkylation; benzene alkylation; mechanism; zeolite catalysts;
D O I：
10.1016/j.molcata.2006.03.068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review paper presents the significant advances which were made in the last decade in the understanding of the transformation over acid and bifunctional zeolite catalysts of the cheap and readily available C-2-C-4 alkanes into more valuable products: mechanism of activation, reaction scheme, nature of the active sites. Both the transformations of pure alkanes: n-butane isomerization, C2-C4 alkane aromatization and of alkanes in mixture with alkenes: isobutane-butene alkylation or with aromatic hydrocarbons: benzene alkylation with ethane or propane are considered. (c) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：131 / 158
页数：28
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