Synthesis, crystal structure and characterization of a lanthanide complex based on 4-(4-oxypyridinium-1-yl) phthalic acid and 1,10-phenanthroline

被引:3
作者
Zhang, Tian [1 ]
Li, Rong Fang [1 ]
Feng, Xun [1 ]
Ng, Seik Weng [2 ,3 ]
Bai, Ruo Fei [1 ]
机构
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
[2] Univ Malaya, Dept Chem, Kuala Lumpur, Malaysia
[3] King Abdulaziz Univ, Chem Dept, Fac Sci, Jeddah, Saudi Arabia
基金
中国国家自然科学基金;
关键词
4-(4-Oxypyridinium-1-yl) phthalic acid; coordination polymer; crystal structure; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMER; GAS-ADSORPTION; LIGAND; SERIES; PHOTOLUMINESCENCE; PROPERTY; CD(II);
D O I
10.1080/15533174.2016.1186065
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new lanthanide complex [(Ho(L)(phen)NO3(H2O)]center dot H2O (1) (H2L = 4-(4-Oxypyridinium -1-yl) phthalic acid, phen = 1,10-phenanthroline) has been afforded under hydrothermal conditions, and characterized by elemental analysis, IR spectra, and X-ray diffraction. In the structure of 1, the L ligand connects Ho(III) atoms through one monodentate and one chelate carboxylate as well as one hydroxy group giving rise to a 2D wavelike polymer layer, which is extended by C-H center dot center dot center dot O hydrogen bond and pi center dot center dot center dot pi stacking interactions to give rise to a 3D supramolecular network. In addition, PXRD patterns and thermal gravimetric analysis (TGA) of sample 1 were investigated.
引用
收藏
页码:375 / 379
页数:5
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