Rheological Characteristics of Highly Concentrated Polymer Bonded Explosive Simulant: Wall Slip, Thixotropy, and Flow Instability

被引:3
作者
Lee, Sangmook [1 ]
Hong, In-Kwon [1 ]
Ahn, Youngjoon [2 ]
Lee, Jae Wook [2 ]
机构
[1] Dankook Univ, Div Chem Engn, Yongin 448701, Gyeonggi Do, South Korea
[2] Sogang Univ, Appl Rheol Ctr, Dept Biomol & Chem Engn, Seoul 121742, South Korea
关键词
polymer bonded explosive; simulant; wall slip; thixotropy; flow instability; POISEUILLE FLOW; SUSPENSIONS; CAPILLARIES; SPHERES;
D O I
10.7317/pk.2014.38.2.213
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The rheological characteristics of highly concentrated polymer bonded explosive simulant were studied. Hydroxyl terminated polybutadiene (HTPB) and polyethylene plastomer (Exact) were used as binders. Sugar and Dechlorane particles whose physical properties are similar to research department explosive (RDX) were used as fillers. When HTPB was used, diethyl hexyl adipate (DEHA or DOA) was used as a plasticizer together for some cases. Highly concentrated suspensions were mixed in a batch melt mixer (Rheomixer 600, Haake) and rheological properties were measured by plate-plate and capillary rheometers. Wall slip phenomena, thixotropy with shear hysteresis, and flow instability were investigated as shear rate and amount of fillers changed.
引用
收藏
页码:213 / 219
页数:7
相关论文
共 28 条
[1]  
Barnes H., 1989, An Introduction to Rheology
[2]   UNSTABLE FLOW OF AMORPHOUS POLYMERS THROUGH CAPILLARIES .1. VELOCITY PROFILES OF POLYMER HAVING DISCONTINUOUS FLOW CURVE [J].
BARTOS, O ;
HOLOMEK, J .
POLYMER ENGINEERING AND SCIENCE, 1971, 11 (04) :324-&
[3]   RHEOLOGICAL STUDIES ON STERICALLY STABILIZED MODEL DISPERSIONS OF UNIFORM COLLOIDAL SPHERES .2. STEADY-SHEAR VISCOSITY [J].
CHOI, GN ;
KRIEGER, IM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 113 (01) :101-113
[4]   APPARENT SLIP-FLOW OF POLYMER-SOLUTIONS [J].
COHEN, Y ;
METZNER, AB .
JOURNAL OF RHEOLOGY, 1985, 29 (01) :67-102
[5]  
Han C.D., 1981, Multiphase Flow in Polymer Processing
[6]   EFFECT OF BROWNIAN MOTION ON RHEOLOGICAL PROPERTIES OF A SUSPENSION OF NON-SPHERICAL PARTICLES [J].
HINCH, EJ ;
LEAL, LG .
JOURNAL OF FLUID MECHANICS, 1972, 52 (APR25) :683-&
[7]  
Hunter R. J., 2001, Foundations of Colloid Science, V2nd ed.
[8]   THE RHEOLOGICAL CHARACTERIZATION OF HPG GELS - MEASUREMENT OF SLIP VELOCITIES IN CAPILLARY TUBES [J].
JIANG, TQ ;
YOUNG, AC ;
METZNER, AB .
RHEOLOGICA ACTA, 1986, 25 (04) :397-404
[9]  
KAMAL MR, 1985, J POLYM ENG, V5, P293
[10]  
Khan S.A., 1987, REV CHEM ENG, V4, P205, DOI [10.1515/REVCE.1987.4.3-4.205, DOI 10.1515/REVCE.1987.4.3-4.205]