Rheological Characteristics of Highly Concentrated Polymer Bonded Explosive Simulant: Wall Slip, Thixotropy, and Flow Instability

被引:3
|
作者
Lee, Sangmook [1 ]
Hong, In-Kwon [1 ]
Ahn, Youngjoon [2 ]
Lee, Jae Wook [2 ]
机构
[1] Dankook Univ, Div Chem Engn, Yongin 448701, Gyeonggi Do, South Korea
[2] Sogang Univ, Appl Rheol Ctr, Dept Biomol & Chem Engn, Seoul 121742, South Korea
关键词
polymer bonded explosive; simulant; wall slip; thixotropy; flow instability; POISEUILLE FLOW; SUSPENSIONS; CAPILLARIES; SPHERES;
D O I
10.7317/pk.2014.38.2.213
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The rheological characteristics of highly concentrated polymer bonded explosive simulant were studied. Hydroxyl terminated polybutadiene (HTPB) and polyethylene plastomer (Exact) were used as binders. Sugar and Dechlorane particles whose physical properties are similar to research department explosive (RDX) were used as fillers. When HTPB was used, diethyl hexyl adipate (DEHA or DOA) was used as a plasticizer together for some cases. Highly concentrated suspensions were mixed in a batch melt mixer (Rheomixer 600, Haake) and rheological properties were measured by plate-plate and capillary rheometers. Wall slip phenomena, thixotropy with shear hysteresis, and flow instability were investigated as shear rate and amount of fillers changed.
引用
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页码:213 / 219
页数:7
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