Synthesis of mesoporous carbon by using polymer blend as template for the high power supercapacitor

被引:24
作者
Chang, Kai-Wen [1 ]
Lim, Zheng-Yi [1 ]
Du, Fang-Yi [1 ]
Yang, Yi-Lin [2 ]
Chang, Chia-Hsien [1 ]
Hu, Chi-Chang [3 ]
Lin, Hong-Ping [1 ,4 ]
机构
[1] Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan
[2] Natl Chung Cheng Univ, Dept Chem Engn, Chiayi 621, Taiwan
[3] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 300, Taiwan
[4] Natl Cheng Kung Univ, Ctr Nano Micro Technol, Tainan 701, Taiwan
关键词
Mesoporous carbon; Polymer blend; Supercapacitor; Gelatin; ELECTRODES; RESIN;
D O I
10.1016/j.diamond.2008.10.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The mesoporous carbon hollow spheres with high surface area, mesoporous shell (pore size >7.0 nm) and macroporous interior (>50.0 nm) have been easily prepared by using gelatin-phenol formaldehyde polymer blend as organic template. Because of short diffusion pathways, the existence of the ion-buffering reservoirs, and the absence of microspores, the mesoporous carbon hollow spheres demonstrate a large specific capacitance of about 132 Fg(-1) at scan rate of 25 mVs(-1), and superior retention (approximate to 90%) in capacitance even at high scan rate to 1000 mVs(-1) In addition, the cyclic voltammetry (CV) profiles of the resulted carbons retain symmetrically rectangular shape at all voltage sweep rate between 25 and 1000 mVs(-1). (c) 2008 Published by Elsevier B.V.
引用
收藏
页码:448 / 451
页数:4
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