Crystal structure of Ni5P2

被引：17

作者：

Oryshchyn, S

Babizhetskyy, V

Chykhriy, S

Aksel'rud, L

Stoyko, S

Bauer, I

Guérin, R

Kuz'ma, Y

机构：

[1] Franko Natl Univ, UA-79005 Lvov, Ukraine

[2] Univ Rennes 1, UMR CNRS 6511, Inst Chim, Lab Chim Solide & Inorgan Mol, F-35042 Rennes, France

[3] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

INORGANIC MATERIALS | 2004年 / 40卷 / 04期

关键词：

D O I：

10.1023/B:INMA.0000023960.30599.22

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

It is shown by x-ray diffraction, energy-dispersive x-ray spectrometry, and electron probe microanalysis that, at 800degreesC, the Ni-P system contains four phosphides in the composition range 25-33 at % P: Ni3P, Ni5P2, Ni12P5, and Ni2P. The structure of Ni5P2 is determined by single-crystal x-ray diffraction: sp. gr. P(3) over bar c1, new structure type, a = 0.6613(3) nm, c = 1.2311(6) nm, 347 independent hkl reflections with F-hkl > 4sigmaG(F-hkl), R-F = 0.0346. The key structural features of Ni5P2 are discussed.

引用

页码：380 / 385

页数：6