Beyond the Icosahedron: The Quest for High-Nuclearity Supraicosahedral Metallaboranes

被引：23
|
作者：
Roy, Dipak Kumar [1 ]
Ghosh, Sundargopal [1 ]
Halet, Jean-Francois [2 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
[2] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes, F-35042 Rennes, France
来源：
JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 01期
关键词：
Boranes; Carboranes; Metallaborane; Metallacarborane; Rhodium; Supraicosahedral clusters; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; BORON HYDRIDE; CP-ASTERISK; HYPOELECTRONIC METALLABORANES; ELECTRONIC-STRUCTURES; BORANE DIANIONS; CHEMISTRY; CLUSTERS; CARBORANES;
D O I：
10.1007/s10876-013-0682-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The recent achievements and progress in the field of high-nuclearity supraicosahedral metallaborane chemistry are reviewed and compared to those made in borane, carborane and metallacarborane chemistry. In contrast to metallacarboranes, characterized large supraicosahedral metallaboranes only adopt isocloso deltahedral structural arrangements with n vertices and a non-Wadean n skeletal-electron-pair count. This anomaly can be rationalized by the preference of metal atoms for 6-connect vertices present in the cluster cages.
引用
收藏
页码：225 / 237
页数：13
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