Beyond the Icosahedron: The Quest for High-Nuclearity Supraicosahedral Metallaboranes

被引：23
|
作者：
Roy, Dipak Kumar [1 ]
Ghosh, Sundargopal [1 ]
Halet, Jean-Francois [2 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
[2] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes, F-35042 Rennes, France
来源：
JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 01期
关键词：
Boranes; Carboranes; Metallaborane; Metallacarborane; Rhodium; Supraicosahedral clusters; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; BORON HYDRIDE; CP-ASTERISK; HYPOELECTRONIC METALLABORANES; ELECTRONIC-STRUCTURES; BORANE DIANIONS; CHEMISTRY; CLUSTERS; CARBORANES;
D O I：
10.1007/s10876-013-0682-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The recent achievements and progress in the field of high-nuclearity supraicosahedral metallaborane chemistry are reviewed and compared to those made in borane, carborane and metallacarborane chemistry. In contrast to metallacarboranes, characterized large supraicosahedral metallaboranes only adopt isocloso deltahedral structural arrangements with n vertices and a non-Wadean n skeletal-electron-pair count. This anomaly can be rationalized by the preference of metal atoms for 6-connect vertices present in the cluster cages.
引用
收藏
页码：225 / 237
页数：13
相关论文
共 50 条
  • [1] Beyond the Icosahedron: The Quest for High-Nuclearity Supraicosahedral Metallaboranes
    Dipak Kumar Roy
    Sundargopal Ghosh
    Jean-François Halet
    Journal of Cluster Science, 2014, 25 : 225 - 237
  • [2] HIGH-NUCLEARITY CLUSTERS
    JOHNSON, BFG
    LEWIS, J
    GALLUP, M
    MARTINELLI, M
    FARADAY DISCUSSIONS, 1991, 92 : 241 - 254
  • [3] High-nuclearity cobaltadendrimers
    Constable, EC
    Eich, O
    Housecroft, CE
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (09): : 1363 - 1364
  • [4] HIGH-NUCLEARITY OXOMOLYBDENUM(V) COMPLEXES
    CHAE, HK
    KLEMPERER, WG
    MARQUART, TA
    COORDINATION CHEMISTRY REVIEWS, 1993, 128 (1-2) : 209 - 224
  • [5] MAGNETISM OF HIGH-NUCLEARITY SPIN CLUSTER
    GATTESCHI, D
    PARDI, L
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1993, 232 : 577 - 590
  • [6] PARAMAGNETISM IN HIGH-NUCLEARITY OSMIUM CLUSTERS
    BENFIELD, RE
    EDWARDS, PP
    STACY, AM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (10) : 525 - 526
  • [7] EXAFS INVESTIGATIONS OF HIGH-NUCLEARITY PD CLUSTERS
    BENFIELD, RE
    FILIPPONI, A
    BOWRON, DT
    NEWPORT, RJ
    GURMAN, SJ
    SCHMID, G
    PHYSICA B, 1995, 208 (1-4): : 671 - 673
  • [8] A high-nuclearity, beyond "fully reduced'' polyoxo(alkoxo) vanadium(III/IV) cage
    Tidmarsh, Ian S.
    Laye, Rebecca H.
    Brearley, Paul R.
    Shanmugam, Maheswaran
    Sanudo, E. Carolina
    Sorace, Lorenzo
    Caneschi, Andrea
    McInnes, Eric J. L.
    CHEMICAL COMMUNICATIONS, 2006, (24) : 2560 - 2562
  • [9] Beyond Anion Template: Polyoxometalate as a Property Influencer in High-Nuclearity Silver Thiolate Cluster
    Ma, Chunyun
    Gui, Kaige
    Xu, Jiaxian
    Lin, Kuishuo
    Ma, Pengtao
    Zhang, Chao
    Wang, Jingping
    Niu, Jingyang
    INORGANIC CHEMISTRY, 2023, 62 (51) : 20980 - 20986
  • [10] EXAFS investigations of high-nuclearity Pd clusters
    Benfield, R.E.
    Filipponi, A.
    Bowron, D.T.
    Newport, R.J.
    Gurman, S.J.
    Schmid, G.
    Physica B: Condensed Matter, 1995, 208-209 (1-4):
12345