Anhydrides from aldehydes or alcohols via oxidative cross-coupling

被引:17
|
作者
Gaspa, Silvia [1 ]
Amura, Ida [1 ]
Porcheddu, Andrea [2 ]
De Luca, Lidia [1 ]
机构
[1] Univ Sassari, Dipartimento Chim & Farm, Via Vienna 2, I-07100 Sassari, Italy
[2] Univ Cagliari, Cittadella Univ, Dipartimento Sci Chim & Geol, I-09042 Monserrato, Italy
关键词
CARBOXYLIC-ACID ANHYDRIDES; ONE-POT SYNTHESIS; SYMMETRICAL ANHYDRIDES; CATALYZED AMIDATION; KINETIC RESOLUTION; HYDROXAMIC ACIDS; ESTERIFICATION; EFFICIENT; ESTERS; DERIVATIVES;
D O I
10.1039/c6nj02625g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel type of metal-free oxidative cross-coupling for the synthesis of symmetrical and mixed anhydrides from aldehydes or benzylic alcohols has been developed. The aldehydes or alcohols were converted in situ into their corresponding acyl chlorides, which were then reacted with an array of carboxylic acids. The methodology has a general applicability, and was successfully employed to prepare either aromatic or aliphatic symmetrical anhydrides and mixed anhydrides, which are very unstable compounds.
引用
收藏
页码:931 / 939
页数:9
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