Morphology-Selective Formation and Morphology-Dependent Gas-Adsorption Properties of Coordination Polymer Particles

被引：112

作者：

Lee, Hee Jung ^{[1
]}

Cho, Won ^{[1
]}

Jung, Soyoung ^{[1
]}

Oh, Moonhyun ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

ADVANCED MATERIALS | 2009年 / 21卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORK; POROUS MATERIAL; INFINITE; CATALYSIS; ACID; SIZE; MICROPARTICLES; NANOPARTICLES; MONODISPERSE; REDUCTION;

D O I：

10.1002/adma.200802485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three coordination polymer particles (CPPs) are selectively synthesized using the solvothermal method. All three CPPs are prepared from the same building blocks. However, they form different morphologies, such as elongated hexagons, ellipsoids, and rods. Gas-adsorption measurements on N-2, CO2, and H-2 reveal that diversely shaped CPPs show different gas-adsorption properties, even though they have the same chemical compositions.

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页码：674 / +

页数：5

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