Solubilities and thermodynamic properties of CO2 in choline-chloride based deep eutectic solvents

被引：133

作者：

Li, Guihua ^{[1
]}

Deng, Dongshun ^{[1
]}

Chen, Yanfei ^{[1
]}

Shan, Haifang ^{[1
]}

Ai, Ning ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Zhejiang Prov Key Lab Biofuel, Hangzhou 310014, Zhejiang, Peoples R China

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2014年 / 75卷

关键词：

Deep eutectic solvents; Carbon dioxide; Solubility; Henry's constant; Thermodynamic properties; TEMPERATURE IONIC LIQUIDS; PRESSURE PHASE-BEHAVIOR; CARBON-DIOXIDE; MIXTURES; TOXICITY; UREA; TETRAFLUOROBORATE; SEPARATION; OXYGEN; LINK;

D O I：

10.1016/j.jct.2014.04.012

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubilities of CO2 in three kinds of deep eutectic solvents, (choline chloride + phenol), (choline chloride + diethylene glycol) and (choline chloride + triethylene glycol), were determined at temperatures ranging from 293.15 K to 323.15 K under pressures up to 600.0 kPa using isochoric saturation method. The mole ratios of choline chloride to phenol were selected as 1:2, 1:3 and 1:4, the others as 1:3 and 1:4. Henry's constants and thermodynamic properties such as standard Gibbs free energy, enthalpy, and entropy changes of CO2 solvation were calculated from the correlation of solubility data. Results revealed that the solubility of CO2 increased with increasing pressure and decreased with increasing temperature. The enthalpies of solution were negative at all conditions. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：58 / 62

页数：5

共 44 条

[1] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].