Magnetic graphene-carbon nanotube iron nanocomposites as adsorbents and antibacterial agents for water purification

被引:130
作者
Sharma, Virender K. [1 ]
McDonald, Thomas J. [1 ]
Kim, Hyunook [2 ]
Garg, Vijayendra K. [3 ]
机构
[1] Texas A&M Univ, Sch Publ Hlth, Dept Environm & Occupat Hlth, College Stn, TX 77843 USA
[2] Univ Seoul, Dept Environm Engn, Seoul 130743, South Korea
[3] Univ Brasilia, Inst Phys, BR-70919970 Brasilia, DF, Brazil
关键词
Magnetic adsorbent; Carbon; Metals; Organics; Arsenic; SOLID-PHASE EXTRACTION; METAL ION REMOVAL; REDUCED GRAPHENE; AQUEOUS-SOLUTION; HEXAVALENT CHROMIUM; EFFICIENT REMOVAL; ACTIVATED CARBON; WASTE-WATER; EXFOLIATED GRAPHENE; FE3O4; NANOPARTICLES;
D O I
10.1016/j.cis.2015.10.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One of the biggest challenges of the 21st century is to provide clean and affordable water through protecting source and purifying polluted waters. This review presents advances made in the synthesis of carbon- and iron-based nanomaterials, graphene-carbon nanotubes-iron oxides, which can remove pollutants and inactivate virus and bacteria efficiently in water. The three-dimensional graphene and graphene oxide based nanostructures exhibit large surface area and sorption sites that provide higher adsorption capacity to remove pollutants than two-dimensional graphene-based adsorbents and other conventional adsorbents. Examples are presented to demonstrate removal of metals (e.g., Cu, Pb, Cr(VI), and As) and organics (e.g., dyes and oil) by grapheme-based nanostructures. Inactivation of Gram-positive and Gram-negative bacterial species (e.g., Escherichia coli and Staphylococcus aureus) is also shown. A mechanism involving the interaction of adsorbents and pollutants is briefly discussed. Magnetic graphene-based nanomaterials can easily be separated from the treated water using an external magnet; however, there are challenges in implementing the graphene-based nanotechnology in treating real water. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:229 / 240
页数:12
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