A review of arsenic interfacial geochemistry in groundwater and the role of organic matter

Recent discoveries on arsenic (As) biogeochemistry in aquifer-sediment system have strongly improved our understanding of As enrichment mechanisms in groundwater. We summarize here the research results since 2015 focusing on the As interfacial geochemistry including As speciation, transformation, and mobilization. We discuss the chemical extraction and speciation of As in environmental matrices, followed by As redox change and (im)mobilization in typical minerals and aquifer system. Then, the microbial-assisted reductive dissolution of Fe (hydr)oxides and As transformation and liberation are summarized from the aspects of bacterial isolates, microbial community and gene analysis by comparing As rich groundwater cases worldwide. Finally, the potential effect of organic matter on As interfacial geochemistry are addressed in the aspects of chemical interactions and microbial respiring activities for Fe and As reductive release.