crystal structures;
lattice dynamics;
high pressure;
D O I:
10.1016/S0921-4526(99)01418-0
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
The structures of ammonium halides ND4I and ND4Br have been studied by means of neutron diffraction at pressures up to 9 GPa. We found that the high-pressure phase V of ammonium halides has the same structure as the low-temperature phase III-tetragonal one with antiparallel ordering of ammonium ions. Vibrational spectra of NH4I have been studied at pressures up to 5 GPa. Libration and transverse optical mode frequencies as functions of pressure were obtained. (C) 2000 Elsevier Science B.V. All rights reserved.