Ternary photocatalyst of atomic-scale Pt coupled with MoS2 co-loaded on TiO2 surface for highly efficient degradation of gaseous toluene

被引:58
|
作者
Qu, Jiafu [1 ]
Chen, Dongyun [1 ]
Li, Najun [1 ]
Xu, Qingfeng [1 ]
Li, Hua [1 ]
He, Jinghui [1 ]
Lu, Jianmei [1 ]
机构
[1] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
TiO2; nanosheets; Molybdenum disulfide; Atomic-scale Pt; Photocatalytic oxidation; Toluene removal; SINGLE-ATOM; OXIDATION; NANOSHEETS; PHOTODEGRADATION; HETEROJUNCTIONS; NANOCOMPOSITES; NANOPARTICLES; IRRADIATION; ADSORPTION; COCATALYST;
D O I
10.1016/j.apcatb.2019.117877
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalysis by semiconducting materials loaded with non-metal or noble metals is an excellent strategy for removal of gaseous toluene. Herein, a new photocatalytic system was successfully prepared via simultaneously coupling atomic-scale Pt with MoS2 as co-catalysts to load on the surface of TiO2. The obtained photocatalysts exhibited good performance in toluene degradation by promoting the separation of photogenerated electron-hole pairs. The most efficient toluene degradation was achieved by the photocatalyst with a content of 2.0 wt% Pt-MT-1.0 (i.e., coupling 2.0 wt% atomic-scale Pt with 1.0 wt% MoS2), with a conversion ratio of 91.5%. This conversion ratio was higher than those of platinum-free MT-1.0 (33.9%) and pure TiO2 (72.3%). The results demonstrate the potential application of this new nanocomposite for efficient photocatalytic degradation of toluene.
引用
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页数:8
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