Synthesis and photophysical investigations of C3-triazine based star-like conjugated molecules

被引:3
作者
Duraimurugan, Kumaraguru [1 ,2 ]
Dhanamoorthy, Vaithialingam [1 ]
Madhavan, Jagannathan [2 ]
Siva, Ayyanar [1 ]
机构
[1] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India
[2] Thiruvalluvar Univ, Dept Chem, Solar Energy Lab, Vellore, Tamil Nadu, India
关键词
C-3-triazine derivatives; Wittig-Horner; Photophysical properties; Aggregation enhanced emission and halochromic; AGGREGATION-INDUCED EMISSION; INTRAMOLECULAR CHARGE-TRANSFER; OPTICAL-PROPERTIES; 2-PHOTON ABSORPTION; LIQUID-CRYSTALLINE; OPTOELECTRONIC PROPERTIES; DERIVATIVES; LUMINESCENT; 1,3,5-TRIAZINE; CARBAZOLE;
D O I
10.1016/j.jphotochem.2018.04.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here, we reported two different C-3-triazine based star-like D-pi-A compounds with a very good yield by Wittig-Horner reaction. Photophysical, aggregation enhanced emission and electrochemical properties were systematically studied. These compounds showed a large halochromic effect on its emission color that changes from greenish-yellow to wine red upon addition of trifluoroacetic acid. Further, the spectral changes are confirmed by H-1 NMR studies. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:164 / 171
页数:8
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