Indole-3-spiro-N-methyl-2′-pyrrolidine-3′-spiro-9"-anthracene-2,10"-dione

被引:14
作者
Ajees, AA
Manikandan, S
Raghunathan, R
机构
[1] Univ Madras, Dept Crystallog & Biophys, Chennai 600025, Tamil Nadu, India
[2] Univ Madras, Dept Organ Chem, Chennai 600025, Tamil Nadu, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷
关键词
D O I
10.1107/S1600536802010863
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C25H20N2O2, contains an enantiomeric pair of molecules, which are linked by N-H...O hydrogen bonds involving N-H and C=O groups of the pyrrole ring. In both molecules, the central six-membered ring of the anthrone moiety adopts a boat conformation, the pyrrolidine ring adopts an envelope conformation and the five-membered ring in the oxindole moiety is slightly distorted from planarity. Both the anthrone and oxindole moieties are almost perpendicular to the pyrrolidine ring.
引用
收藏
页码:O802 / o804
页数:3
相关论文
共 35 条
[1]  
BALDWIN JE, 1994, TETRAHEDRON, V50, P9425, DOI 10.1016/S0040-4020(01)85517-4
[2]   THE SYNTHESIS OF SUBSTITUTED PYRROLIDINES BY A SAMARIUM(II) IODIDE-MEDIATED RING-CLOSURE .1. [J].
BALDWIN, JE ;
MACKENZIETURNER, SC ;
MOLONEY, MG .
TETRAHEDRON, 1994, 50 (31) :9411-9424
[3]   THE GEOMETRY AT NITROGEN IN N-PHENYLSULFONYL-PYRROLES AND N-PHENYLSULFONYL-INDOLES - THE GEOMETRY OF SULFONAMIDES [J].
BEDDOES, RL ;
DALTON, L ;
JOULE, JA ;
MILLS, OS ;
STREET, JD ;
WATT, CIF .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1986, (06) :787-797
[4]  
*BIOSYM MSI, 1995, BIOSYM REL 95 0
[5]   GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].
CREMER, D ;
POPLE, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358
[6]   STRUCTURE OF HARMAN, 1-METHYL-9H-PYRIDO[3,4-B]INDOLE [J].
ELSAYED, K ;
BARNHART, DM ;
AMMON, HL ;
WASSEL, GM .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :1383-1385
[7]  
Enraf-Nonius, 1989, CAD 4 SOFTW VERS 5 0
[8]  
FRENZ BA, 1978, ENRAF NONIUS CAD4 SD, P64
[9]  
Gadaginamath GS, 1999, INDIAN J CHEM B, V38, P1070
[10]   Stereoselective reduction of chiral trans-3-acetyl-4-alkylpyrrolidin-2-ones [J].
Galeazzi, R ;
Geremia, S ;
Mobbili, G ;
Orena, M .
TETRAHEDRON-ASYMMETRY, 1999, 10 (03) :587-605