Selective Platinum-Catalyzed C-F Bond Activation as a Route to Fluorinated Aryl Methyl Ethers

被引：57
作者：
Buckley, Heather L. [1 ]
Wang, Tongen [1 ]
Tran, Olivia [1 ]
Love, Jennifer A. [1 ]
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 08期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
CROSS-COUPLING REACTION; REDUCTIVE ELIMINATION-REACTIONS; POTASSIUM FLUORIDE ALUMINA; H ACTIVATION; OXIDATIVE ADDITION; VANCOMYCIN AGLYCON; GRIGNARD-REAGENTS; DIARYL ETHERS; AROMATIC FLUOROALKOXYLATION; MECHANISTIC ASPECTS;
D O I：
10.1021/om900100f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[(CH3)(2)Pt(mu-SMe2)](2)catalyzes the formation of aryl methyl ethers via selective C-F bond activation of polyfluoroarylimines. This reaction is functional group tolerant and proceeds in good to excellent yields. The optimization and preliminary substrate scope of this process are described.
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收藏
页码：2356 / 2359
页数：4
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