Electrodeposited Cu-Pd bimetallic catalysts for the selective electroreduction of CO2 to ethylene

被引：50

作者：

Feng, Ruting ^{[1
]}

Zhu, Qinggong ^{[2
]}

Chu, Mengen ^{[1
]}

Jia, Shuaiqiang ^{[1
]}

Zhai, Jianxin ^{[1
]}

Wu, Haihong ^{[1
]}

Wu, Peng ^{[1
]}

Han, Buxing ^{[1
,2
]}

机构：

[1] East China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China

[2] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Zhongguancun North First St 2, Beijing 100190, Peoples R China

来源：

GREEN CHEMISTRY | 2020年 / 22卷 / 21期

基金：

中国国家自然科学基金;

关键词：

EFFICIENT ELECTROCATALYTIC REDUCTION; CARBON-DIOXIDE REDUCTION; ELECTROCHEMICAL REDUCTION; COPPER-CATALYSTS; NANOSHEETS; PRODUCTS; NANOPARTICLES; ETHANOL;

D O I：

10.1039/d0gc03051a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu-Pd bimetallic catalysts were fabricated on carbon paper (CP) by the electrodeposition method via a dynamic hydrogen bubble template approach. At a potential of -1.2 V vs. RHE, the Faradaic efficiency (FE) of C2H4 could reach 45.2% with a current density of 17.4 mA cm(-2) in an H-type electrolytic cell. Detailed studies suggest that the enhanced performance of Cu-Pd/CP was attributed mainly to the synergistic effect, low interfacial charge transfer resistance, and the 3D architecture of the catalysts.

引用

页码：7560 / 7565

页数：6

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