Microwave-assisted hydrothermal synthesis of a&b-oriented zeolite T membranes and their pervaporation properties

被引：67
|
作者：
Zhou, Han [1 ,2 ]
Li, Yanshuo [1 ]
Zhu, Guangqi [1 ,2 ]
Liu, Jie [1 ]
Yang, Weishen [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
来源：
SEPARATION AND PURIFICATION TECHNOLOGY | 2009年 / 65卷 / 02期
基金：
美国国家科学基金会;
关键词：
Zeolite membrane; Microwave synthesis; Pervaporation; Membrane stability; Inorganic membrane; SILICALITE-1; MEMBRANES; PERMEATION PROPERTIES; MFI FILMS; SEPARATION; MIXTURES; DEHYDRATION; PERFORMANCE; GROWTH;
D O I：
10.1016/j.seppur.2008.10.046
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
By microwave-assisted hydrothermal synthesis (MAHS) method, a&b-oriented zeolite T membranes were firstly prepared on the alpha-Al2O3 tubes from the a&b-oriented seed layers. By adjusting the pH value of the seed suspension, zeolite T seeds about 8.5 mu m long were uniformly deposited on the support surface with their a&b-axes perpendicular to the support surface. After the secondary growth, the a&b-oriented seed layers grew into a&b-oriented zeolite T membranes with the thickness of about 7 mu m. A formation mechanism of the membranes was proposed, which could provide general guidance for the preparation of other types of zeolite membranes. The as-synthesized membranes displayed high pervaporation (PV) performance for alcohol/water liquid mixtures. Aiming at the application in the industrial dehydration process, the hydrothermal stability and acid stability of the zeolite T membranes were also investigated. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：164 / 172
页数：9
相关论文
共 50 条
  • [1] Microwave synthesis of a&b-oriented zeolite T membranes and their application in pervaporation-assisted esterification
    Zhou Han
    Li Yanshuo
    Zhu Guangqi
    Liu Jie
    Lin Liwu
    Yang Weishen
    CHINESE JOURNAL OF CATALYSIS, 2008, 29 (07) : 592 - 594
  • [2] Microwave-assisted hydrothermal rapid synthesis of capillary MFI-type zeolite-ceramic membranes for pervaporation application
    Sebastian, Victor
    Mallada, Reyes
    Coronas, Joaquin
    Julbe, Anne
    Terpstra, Rinse A.
    Dirrix, Ruud W. J.
    JOURNAL OF MEMBRANE SCIENCE, 2010, 355 (1-2) : 28 - 35
  • [3] Synthesis, characterization and pervaporation properties of microwave synthesized zeolite A membrane
    Ling, Wee Shin
    Thian, Tye Ching
    Bhatia, Subhash
    DESALINATION, 2011, 277 (1-3) : 383 - 389
  • [4] Synthesis of oriented zeolite T membranes from clear solutions and their pervaporation properties
    Zhou, Rongfei
    Hu, Lili
    Zhang, Youjun
    Hu, Na
    Chen, Xiangshu
    Lin, Xiao
    Kita, Hidetoshi
    MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 174 : 81 - 89
  • [5] Preparation of zeolite T membranes by microwave-assisted in situ nucleation and secondary growth
    Zhou, Han
    Li, Yanshuo
    Zhu, Guangqi
    Liu, Jie
    Yang, Weishen
    MATERIALS LETTERS, 2009, 63 (02) : 255 - 257
  • [6] Microwave-assisted hydrothermal synthesis of mordenite zeolite: Optimization of synthesis parameters
    Khalil, Umer
    Muraza, Old
    MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 232 : 211 - 217
  • [7] Microwave-Assisted Hydrothermal Synthesis of CHA Zeolite for Methanol-to-Olefins Reaction
    Nasser, Galal A.
    Muraza, Oki
    Nishitoba, Toshiki
    Malaibari, Zuhair
    Yamani, Zain H.
    Al-Shammari, Talal K.
    Yokoi, Toshiyuki
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (01) : 60 - 68
  • [8] Synthesis, Characterization and Pervaporation Performances of Zeolite T Membranes
    Zhou Rong-Fei
    Hu Na
    Yuan Hui
    Zhu Mei-Hua
    Wang Zhen-Zhuo
    Chen Xiang-Shu
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (08) : 1439 - 1446
  • [9] Microwave-assisted hydrothermal synthesis of hydroxy-sodalite zeolite membrane
    Xu, XC
    Bao, Y
    Song, CS
    Yang, WS
    Liu, J
    Lin, LW
    MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 75 (03) : 173 - 181
  • [10] Synthesis of capillary titanosilicalite TS-1 ceramic membranes by MW-assisted hydrothermal heating for pervaporation application
    Sebastian, Victor
    Motuzas, Julius
    Dirrix, Ruud W. J.
    Terpstra, Rinse A.
    Mallada, Reyes
    Julbe, Anne
    SEPARATION AND PURIFICATION TECHNOLOGY, 2010, 75 (03) : 249 - 256
12345