Hydroxyalkylation of barbituric acid. I. Hydroxymethyl derivatives of barbituric acid - Precursors of polyetherols with a pyrimidine ring

被引:9
|
作者
Slaczka, Anna [1 ]
Lubczak, Jacek [1 ]
机构
[1] Rzeszow Univ Technol, Dept Organ Chem, PL-35959 Rzeszow, Poland
关键词
addition polymerization; oligomers; structure-property relations; resins;
D O I
10.1002/app.24356
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The reaction of barbituric acid with formaldehyde at variable molar ratios was studied. The structure of the products was elucidated using H-1-NMR and IR spectroscopy as well as acidic number and formaldehyde percentage analysis. The products were potential substrates for the synthesis of linear and multifunctional polyetherols with a pyrimidine ring by reaction with oxiranes. (c) 2006 Wiley Periodicals, Inc.
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页码:3468 / 3478
页数:11
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