Synthesis, Characterization and Thermal Behavior of Two 4d-4f Coordination Polymers Based on N and O Donor Ligands

被引：15
|
作者：
Lian, Qing-Yang [1 ,2 ,3 ]
Huang, Chun-De [1 ,2 ,3 ]
Zeng, Rong-Hua [1 ,2 ,3 ]
Qiu, Yong-Cai [1 ,2 ,3 ]
Mou, Ji-Xia [1 ,2 ,3 ]
Deng, Hong. [1 ,2 ,3 ]
Zeller, Matthias [4 ]
机构：
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] Key Lab Electrochem Technol Energy Storage, Guangzhou 510631, Guangdong, Peoples R China
[3] Power Generat Guangdong Univ, Guangzhou 510631, Guangdong, Peoples R China
[4] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 02期
关键词：
Nicotinic acid; Isonicotinic acid; 4d-4f systems; Crystal structures; Heterometallic coordination polymers; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; MOLECULAR-STRUCTURE; LANTHANIDE IONS; COMPLEXES; GD; LN; CONSTRUCTION; ARCHITECTURE;
D O I：
10.1002/zaac.200800363
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new 4d-4f coordination polymers, [Ag2Nd(nic)(4)(H2O)(4)center dot(ClO4)center dot H2O] (1) and [Ag8Yb4(inic)(8)(ox)(6)] (Ag-2(inic)(2)] (2) [nic = nicotinate, inic = isonicotinate and ox = oxalate] have been synthesized and characterized by element analysis, IR spectroscopy and thermal analysis, as well as single crystal X-ray diffraction. Complex 1 exhibits a wavelike layer that is assembled from neodymium-carboxylate subunits, silver centres and perchlorate ions. Complex 2 represents a extended heterometallic sandwich-like layered network that is constructed from ytterbium-oxalate layers and Ag(inic) chains.
引用
收藏
页码：393 / 398
页数：6
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